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Self-assembly of protonated 1,12-dodecanediamine molecules and strongly undulated uranyl selenate sheets in the structure of amine-templated uranyl selenate:(H3O)2[C12H30N 2]3[(UO2)4(SeO4) 8](H2O)5. / Krivovichev, Sergey V.; Kahlenberg, Volker; Avdontseva, Evgeniya Yu; Mersdorf, Edgar; Kaindl, Reinhard.

In: European Journal of Inorganic Chemistry, No. 9, 06.05.2005, p. 1653-1656.

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@article{d85488eabcb643449dd91aac57281cdc,
title = "Self-assembly of protonated 1,12-dodecanediamine molecules and strongly undulated uranyl selenate sheets in the structure of amine-templated uranyl selenate:(H3O)2[C12H30N 2]3[(UO2)4(SeO4) 8](H2O)5",
abstract = "The amine-templated uranyl selenate (H3O)2[C 12H30N2]3-[(UO2) 4(SeO4)8](H2O)5 (1) has been prepared. Its structure [monoclinic, P21/n, a = 11.3437(7), b = 24.8042(12), c = 29.2496(19) {\AA}, β= 96.701(5)°, V = 8173.8(8) {\AA}3, Z = 4, R1 = 0.083] is based upon strongly undulating [(UO2)(SeO4)2]2- sheets consisting of corner-sharing UO7 bipyramids and SeO4 2- tetrahedra. The undulations of the adjacent sheets have an anti-phase character that allows the formation of large eliptical channels that are occupied by rod micelles formed by self-assembly of protonated 1,12-dodecanediamine molecules.",
keywords = "Host-guest systems, Layered compounds, Selenium, Self-assembly, Uranium",
author = "Krivovichev, {Sergey V.} and Volker Kahlenberg and Avdontseva, {Evgeniya Yu} and Edgar Mersdorf and Reinhard Kaindl",
year = "2005",
month = may,
day = "6",
doi = "10.1002/ejic.200500057",
language = "English",
pages = "1653--1656",
journal = "Berichte der deutschen chemischen Gesellschaft",
issn = "0365-9496",
publisher = "Wiley-Blackwell",
number = "9",

}

RIS

TY - JOUR

T1 - Self-assembly of protonated 1,12-dodecanediamine molecules and strongly undulated uranyl selenate sheets in the structure of amine-templated uranyl selenate:(H3O)2[C12H30N 2]3[(UO2)4(SeO4) 8](H2O)5

AU - Krivovichev, Sergey V.

AU - Kahlenberg, Volker

AU - Avdontseva, Evgeniya Yu

AU - Mersdorf, Edgar

AU - Kaindl, Reinhard

PY - 2005/5/6

Y1 - 2005/5/6

N2 - The amine-templated uranyl selenate (H3O)2[C 12H30N2]3-[(UO2) 4(SeO4)8](H2O)5 (1) has been prepared. Its structure [monoclinic, P21/n, a = 11.3437(7), b = 24.8042(12), c = 29.2496(19) Å, β= 96.701(5)°, V = 8173.8(8) Å3, Z = 4, R1 = 0.083] is based upon strongly undulating [(UO2)(SeO4)2]2- sheets consisting of corner-sharing UO7 bipyramids and SeO4 2- tetrahedra. The undulations of the adjacent sheets have an anti-phase character that allows the formation of large eliptical channels that are occupied by rod micelles formed by self-assembly of protonated 1,12-dodecanediamine molecules.

AB - The amine-templated uranyl selenate (H3O)2[C 12H30N2]3-[(UO2) 4(SeO4)8](H2O)5 (1) has been prepared. Its structure [monoclinic, P21/n, a = 11.3437(7), b = 24.8042(12), c = 29.2496(19) Å, β= 96.701(5)°, V = 8173.8(8) Å3, Z = 4, R1 = 0.083] is based upon strongly undulating [(UO2)(SeO4)2]2- sheets consisting of corner-sharing UO7 bipyramids and SeO4 2- tetrahedra. The undulations of the adjacent sheets have an anti-phase character that allows the formation of large eliptical channels that are occupied by rod micelles formed by self-assembly of protonated 1,12-dodecanediamine molecules.

KW - Host-guest systems

KW - Layered compounds

KW - Selenium

KW - Self-assembly

KW - Uranium

UR - http://www.scopus.com/inward/record.url?scp=18844388983&partnerID=8YFLogxK

U2 - 10.1002/ejic.200500057

DO - 10.1002/ejic.200500057

M3 - Article

AN - SCOPUS:18844388983

SP - 1653

EP - 1656

JO - Berichte der deutschen chemischen Gesellschaft

JF - Berichte der deutschen chemischen Gesellschaft

SN - 0365-9496

IS - 9

ER -

ID: 49256819