Standard

Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile. / Rozhkov, Anton V.; Krykova, Mariya A.; Ivanov, Daniil M.; Novikov, Alexander S.; Sinelshchikova, Anna A.; Volostnykh, Marina V.; Konovalov, Mikhail A.; Grigoriev, Mikhail S.; Gorbunova, Yulia G.; Kukushkin, Vadim Yu.

в: Angewandte Chemie - International Edition, Том 58, № 13, 22.03.2019, стр. 4164-4168.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Rozhkov, AV, Krykova, MA, Ivanov, DM, Novikov, AS, Sinelshchikova, AA, Volostnykh, MV, Konovalov, MA, Grigoriev, MS, Gorbunova, YG & Kukushkin, VY 2019, 'Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile', Angewandte Chemie - International Edition, Том. 58, № 13, стр. 4164-4168. https://doi.org/10.1002/anie.201814062

APA

Rozhkov, A. V., Krykova, M. A., Ivanov, D. M., Novikov, A. S., Sinelshchikova, A. A., Volostnykh, M. V., Konovalov, M. A., Grigoriev, M. S., Gorbunova, Y. G., & Kukushkin, V. Y. (2019). Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile. Angewandte Chemie - International Edition, 58(13), 4164-4168. https://doi.org/10.1002/anie.201814062

Vancouver

Rozhkov AV, Krykova MA, Ivanov DM, Novikov AS, Sinelshchikova AA, Volostnykh MV и пр. Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile. Angewandte Chemie - International Edition. 2019 Март 22;58(13):4164-4168. https://doi.org/10.1002/anie.201814062

Author

Rozhkov, Anton V. ; Krykova, Mariya A. ; Ivanov, Daniil M. ; Novikov, Alexander S. ; Sinelshchikova, Anna A. ; Volostnykh, Marina V. ; Konovalov, Mikhail A. ; Grigoriev, Mikhail S. ; Gorbunova, Yulia G. ; Kukushkin, Vadim Yu. / Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile. в: Angewandte Chemie - International Edition. 2019 ; Том 58, № 13. стр. 4164-4168.

BibTeX

@article{660acf17ba0b4be1bd5e68d5c74d78fa,
title = "Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile",
abstract = " The complexes [Pt(tpp)] (H 2 tpp=tetraphenylporphyrin), [M(acac) 2 ] (M=Pd, Pt, Hacac=acetylacetone), and [Pd(ba) 2 ] (Hba=benzoylacetone) were co-crystallized with highly electron-deficient arene systems to form reverse arene sandwich structures built by π-hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) interactions. The adduct [Pt(tpp)]⋅2 C 6 F 6 is monomeric, whereas the diketonate 1:1 adducts form columnar infinity 1D-stack assembled by simultaneous action of both π-hole⋅⋅⋅[M II ] and C⋅⋅⋅F interactions. The reverse sandwiches are based on noncovalent interactions and calculated ESP distributions indicate that in π-hole⋅⋅⋅[M II ] contacts, [M II ] plays the role of a nucleophile. ",
keywords = "noncovalent interactions, palladium, platinum, reverse sandwich complexes, π-hole interactions, HOLE, -hole interactions, ACID, COMPLEXES, PLATINUM, OXIDATIVE ADDITION, MOLECULES",
author = "Rozhkov, {Anton V.} and Krykova, {Mariya A.} and Ivanov, {Daniil M.} and Novikov, {Alexander S.} and Sinelshchikova, {Anna A.} and Volostnykh, {Marina V.} and Konovalov, {Mikhail A.} and Grigoriev, {Mikhail S.} and Gorbunova, {Yulia G.} and Kukushkin, {Vadim Yu}",
year = "2019",
month = mar,
day = "22",
doi = "10.1002/anie.201814062",
language = "English",
volume = "58",
pages = "4164--4168",
journal = "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION",
issn = "1433-7851",
publisher = "Wiley-Blackwell",
number = "13",

}

RIS

TY - JOUR

T1 - Reverse Arene Sandwich Structures Based upon π-Hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) Interactions, where Positively Charged Metal Centers Play the Role of a Nucleophile

AU - Rozhkov, Anton V.

AU - Krykova, Mariya A.

AU - Ivanov, Daniil M.

AU - Novikov, Alexander S.

AU - Sinelshchikova, Anna A.

AU - Volostnykh, Marina V.

AU - Konovalov, Mikhail A.

AU - Grigoriev, Mikhail S.

AU - Gorbunova, Yulia G.

AU - Kukushkin, Vadim Yu

PY - 2019/3/22

Y1 - 2019/3/22

N2 - The complexes [Pt(tpp)] (H 2 tpp=tetraphenylporphyrin), [M(acac) 2 ] (M=Pd, Pt, Hacac=acetylacetone), and [Pd(ba) 2 ] (Hba=benzoylacetone) were co-crystallized with highly electron-deficient arene systems to form reverse arene sandwich structures built by π-hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) interactions. The adduct [Pt(tpp)]⋅2 C 6 F 6 is monomeric, whereas the diketonate 1:1 adducts form columnar infinity 1D-stack assembled by simultaneous action of both π-hole⋅⋅⋅[M II ] and C⋅⋅⋅F interactions. The reverse sandwiches are based on noncovalent interactions and calculated ESP distributions indicate that in π-hole⋅⋅⋅[M II ] contacts, [M II ] plays the role of a nucleophile.

AB - The complexes [Pt(tpp)] (H 2 tpp=tetraphenylporphyrin), [M(acac) 2 ] (M=Pd, Pt, Hacac=acetylacetone), and [Pd(ba) 2 ] (Hba=benzoylacetone) were co-crystallized with highly electron-deficient arene systems to form reverse arene sandwich structures built by π-hole⋅⋅⋅[M II ] (d 8 M=Pt, Pd) interactions. The adduct [Pt(tpp)]⋅2 C 6 F 6 is monomeric, whereas the diketonate 1:1 adducts form columnar infinity 1D-stack assembled by simultaneous action of both π-hole⋅⋅⋅[M II ] and C⋅⋅⋅F interactions. The reverse sandwiches are based on noncovalent interactions and calculated ESP distributions indicate that in π-hole⋅⋅⋅[M II ] contacts, [M II ] plays the role of a nucleophile.

KW - noncovalent interactions

KW - palladium

KW - platinum

KW - reverse sandwich complexes

KW - π-hole interactions

KW - HOLE

KW - -hole interactions

KW - ACID

KW - COMPLEXES

KW - PLATINUM

KW - OXIDATIVE ADDITION

KW - MOLECULES

UR - http://www.scopus.com/inward/record.url?scp=85061599443&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/reverse-arene-sandwich-structures-based-upon-%CF%80holem-ii-d-8-mpt-pd-interactions-positively-charged-m

U2 - 10.1002/anie.201814062

DO - 10.1002/anie.201814062

M3 - Article

AN - SCOPUS:85061599443

VL - 58

SP - 4164

EP - 4168

JO - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

JF - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SN - 1433-7851

IS - 13

ER -

ID: 39316018