Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers. / Kirillov, Evgueni ; Rodygin, Konstantin ; Ananikov, Valentine .
в: European Polymer Journal, Том 136, 109872, 05.08.2020.Результаты исследований: Научные публикации в периодических изданиях › Обзорная статья › Рецензирование
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TY - JOUR
T1 - Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers
AU - Kirillov, Evgueni
AU - Rodygin, Konstantin
AU - Ananikov, Valentine
PY - 2020/8/5
Y1 - 2020/8/5
N2 - This review highlights recent progress in the synthesis and application of vinyl ethers (VEs) as monomers for modern homo- and co-polymerization processes. VEs can be easily prepared using a number of traditional synthetic protocols including a more sustainable and straightforward manner by reacting gaseous acetylene or calcium carbide with alcohols. The remarkably tunable chemistry of VEs allows designing and obtaining polymers with well-defined structures and controllable properties. Both VE homopolymerization and copolymerization systems are considered, and specific emphasis is given to the novel initiating systems and to the methods of stereocontrol.
AB - This review highlights recent progress in the synthesis and application of vinyl ethers (VEs) as monomers for modern homo- and co-polymerization processes. VEs can be easily prepared using a number of traditional synthetic protocols including a more sustainable and straightforward manner by reacting gaseous acetylene or calcium carbide with alcohols. The remarkably tunable chemistry of VEs allows designing and obtaining polymers with well-defined structures and controllable properties. Both VE homopolymerization and copolymerization systems are considered, and specific emphasis is given to the novel initiating systems and to the methods of stereocontrol.
KW - Poly(vinyl ethers)
KW - Polymerization mechanism
KW - Stereocontrol in polymerization
KW - Vinyl ethers
KW - BLOCK-COPOLYMERS
KW - BENIGN INITIATING SYSTEM
KW - LIVING CATIONIC-POLYMERIZATION
KW - SHAPED POLY(VINYL ETHER)S
KW - RING-OPENING COPOLYMERIZATION
KW - DIRECT RADICAL POLYMERIZATION
KW - CALCIUM CARBIDE
KW - RAFT POLYMERIZATION
KW - P-METHOXYSTYRENE
KW - LEWIS-ACIDS
UR - http://www.scopus.com/inward/record.url?scp=85088917985&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/c9c8db04-ac57-3556-a4d2-be091e76817e/
U2 - 10.1016/j.eurpolymj.2020.109872
DO - 10.1016/j.eurpolymj.2020.109872
M3 - Review article
VL - 136
JO - European Polymer Journal
JF - European Polymer Journal
SN - 0014-3057
M1 - 109872
ER -
ID: 61434334