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Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers. / Kirillov, Evgueni ; Rodygin, Konstantin ; Ananikov, Valentine .

In: European Polymer Journal, Vol. 136, 109872, 05.08.2020.

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Kirillov, Evgueni ; Rodygin, Konstantin ; Ananikov, Valentine . / Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers. In: European Polymer Journal. 2020 ; Vol. 136.

BibTeX

@article{f2b4476aaf2b4c89becc4beef21a4d5a,
title = "Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers",
abstract = "This review highlights recent progress in the synthesis and application of vinyl ethers (VEs) as monomers for modern homo- and co-polymerization processes. VEs can be easily prepared using a number of traditional synthetic protocols including a more sustainable and straightforward manner by reacting gaseous acetylene or calcium carbide with alcohols. The remarkably tunable chemistry of VEs allows designing and obtaining polymers with well-defined structures and controllable properties. Both VE homopolymerization and copolymerization systems are considered, and specific emphasis is given to the novel initiating systems and to the methods of stereocontrol.",
keywords = "Poly(vinyl ethers), Polymerization mechanism, Stereocontrol in polymerization, Vinyl ethers, BLOCK-COPOLYMERS, BENIGN INITIATING SYSTEM, LIVING CATIONIC-POLYMERIZATION, SHAPED POLY(VINYL ETHER)S, RING-OPENING COPOLYMERIZATION, DIRECT RADICAL POLYMERIZATION, CALCIUM CARBIDE, RAFT POLYMERIZATION, P-METHOXYSTYRENE, LEWIS-ACIDS",
author = "Evgueni Kirillov and Konstantin Rodygin and Valentine Ananikov",
year = "2020",
month = aug,
day = "5",
doi = "10.1016/j.eurpolymj.2020.109872",
language = "English",
volume = "136",
journal = "European Polymer Journal",
issn = "0014-3057",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers

AU - Kirillov, Evgueni

AU - Rodygin, Konstantin

AU - Ananikov, Valentine

PY - 2020/8/5

Y1 - 2020/8/5

N2 - This review highlights recent progress in the synthesis and application of vinyl ethers (VEs) as monomers for modern homo- and co-polymerization processes. VEs can be easily prepared using a number of traditional synthetic protocols including a more sustainable and straightforward manner by reacting gaseous acetylene or calcium carbide with alcohols. The remarkably tunable chemistry of VEs allows designing and obtaining polymers with well-defined structures and controllable properties. Both VE homopolymerization and copolymerization systems are considered, and specific emphasis is given to the novel initiating systems and to the methods of stereocontrol.

AB - This review highlights recent progress in the synthesis and application of vinyl ethers (VEs) as monomers for modern homo- and co-polymerization processes. VEs can be easily prepared using a number of traditional synthetic protocols including a more sustainable and straightforward manner by reacting gaseous acetylene or calcium carbide with alcohols. The remarkably tunable chemistry of VEs allows designing and obtaining polymers with well-defined structures and controllable properties. Both VE homopolymerization and copolymerization systems are considered, and specific emphasis is given to the novel initiating systems and to the methods of stereocontrol.

KW - Poly(vinyl ethers)

KW - Polymerization mechanism

KW - Stereocontrol in polymerization

KW - Vinyl ethers

KW - BLOCK-COPOLYMERS

KW - BENIGN INITIATING SYSTEM

KW - LIVING CATIONIC-POLYMERIZATION

KW - SHAPED POLY(VINYL ETHER)S

KW - RING-OPENING COPOLYMERIZATION

KW - DIRECT RADICAL POLYMERIZATION

KW - CALCIUM CARBIDE

KW - RAFT POLYMERIZATION

KW - P-METHOXYSTYRENE

KW - LEWIS-ACIDS

UR - http://www.scopus.com/inward/record.url?scp=85088917985&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/c9c8db04-ac57-3556-a4d2-be091e76817e/

U2 - 10.1016/j.eurpolymj.2020.109872

DO - 10.1016/j.eurpolymj.2020.109872

M3 - Review article

VL - 136

JO - European Polymer Journal

JF - European Polymer Journal

SN - 0014-3057

M1 - 109872

ER -

ID: 61434334