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Reactivity of the stibinidene complex [ClSb{Cr(CO)5}2(thf)]. / Rummel, Lena; Seidl, Michael; Timoshkin, Alexey Y.; Scheer, Manfred.

в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 648, № 13, e202200014, 14.07.2022.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Rummel, L, Seidl, M, Timoshkin, AY & Scheer, M 2022, 'Reactivity of the stibinidene complex [ClSb{Cr(CO)5}2(thf)]', Zeitschrift fur Anorganische und Allgemeine Chemie, Том. 648, № 13, e202200014. https://doi.org/10.1002/zaac.202200014

APA

Rummel, L., Seidl, M., Timoshkin, A. Y., & Scheer, M. (2022). Reactivity of the stibinidene complex [ClSb{Cr(CO)5}2(thf)]. Zeitschrift fur Anorganische und Allgemeine Chemie, 648(13), [e202200014]. https://doi.org/10.1002/zaac.202200014

Vancouver

Rummel L, Seidl M, Timoshkin AY, Scheer M. Reactivity of the stibinidene complex [ClSb{Cr(CO)5}2(thf)]. Zeitschrift fur Anorganische und Allgemeine Chemie. 2022 Июль 14;648(13). e202200014. https://doi.org/10.1002/zaac.202200014

Author

Rummel, Lena ; Seidl, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred. / Reactivity of the stibinidene complex [ClSb{Cr(CO)5}2(thf)]. в: Zeitschrift fur Anorganische und Allgemeine Chemie. 2022 ; Том 648, № 13.

BibTeX

@article{1a89555e828546bcb16126740645b2cb,
title = "Reactivity of the stibinidene complex [ClSb{Cr(CO)5}2(thf)]",
abstract = "Stibinidene complexes are rare and highly sensitive low-valent main group compounds, which have not been studied extensively for their reaction behavior so far. In the reaction with GaCl3, the stibinidene complex [ClSb{Cr(CO)5}2(thf)] (1) shows a dimerization to [ClSb{Cr(CO)5}2]2 (2) and yields the anionic double-chlorinated compound [Cl2Sb{Cr(CO)5}2]− (3) in the reaction with different ionic nucleophiles. When using neutral nucleophiles (such as amines, isocyanides and phosphines) as reaction partners, tetrahedral complexes of the type [ClSb{Cr(CO)5}2Nu] (4: Nu=NH2Mes; 5: Nu=CN(dmp); 6: Nu=PPh3; 7: Nu=PPh2H) are formed which can be used in subsequent reactions. All of these products are among the first of their type to be synthesized and isolated.",
keywords = "antimony, complexes, main group chemistry, reactivity, stibinidenes, ARSINIDENE, MO, ANTIMONY(I), LIGAND, CR, SB",
author = "Lena Rummel and Michael Seidl and Timoshkin, {Alexey Y.} and Manfred Scheer",
note = "Publisher Copyright: {\textcopyright} 2022 The Authors. Zeitschrift f{\"u}r anorganische und allgemeine Chemie published by Wiley-VCH GmbH",
year = "2022",
month = jul,
day = "14",
doi = "10.1002/zaac.202200014",
language = "English",
volume = "648",
journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",
issn = "0044-2313",
publisher = "Wiley-Blackwell",
number = "13",

}

RIS

TY - JOUR

T1 - Reactivity of the stibinidene complex [ClSb{Cr(CO)5}2(thf)]

AU - Rummel, Lena

AU - Seidl, Michael

AU - Timoshkin, Alexey Y.

AU - Scheer, Manfred

N1 - Publisher Copyright: © 2022 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH

PY - 2022/7/14

Y1 - 2022/7/14

N2 - Stibinidene complexes are rare and highly sensitive low-valent main group compounds, which have not been studied extensively for their reaction behavior so far. In the reaction with GaCl3, the stibinidene complex [ClSb{Cr(CO)5}2(thf)] (1) shows a dimerization to [ClSb{Cr(CO)5}2]2 (2) and yields the anionic double-chlorinated compound [Cl2Sb{Cr(CO)5}2]− (3) in the reaction with different ionic nucleophiles. When using neutral nucleophiles (such as amines, isocyanides and phosphines) as reaction partners, tetrahedral complexes of the type [ClSb{Cr(CO)5}2Nu] (4: Nu=NH2Mes; 5: Nu=CN(dmp); 6: Nu=PPh3; 7: Nu=PPh2H) are formed which can be used in subsequent reactions. All of these products are among the first of their type to be synthesized and isolated.

AB - Stibinidene complexes are rare and highly sensitive low-valent main group compounds, which have not been studied extensively for their reaction behavior so far. In the reaction with GaCl3, the stibinidene complex [ClSb{Cr(CO)5}2(thf)] (1) shows a dimerization to [ClSb{Cr(CO)5}2]2 (2) and yields the anionic double-chlorinated compound [Cl2Sb{Cr(CO)5}2]− (3) in the reaction with different ionic nucleophiles. When using neutral nucleophiles (such as amines, isocyanides and phosphines) as reaction partners, tetrahedral complexes of the type [ClSb{Cr(CO)5}2Nu] (4: Nu=NH2Mes; 5: Nu=CN(dmp); 6: Nu=PPh3; 7: Nu=PPh2H) are formed which can be used in subsequent reactions. All of these products are among the first of their type to be synthesized and isolated.

KW - antimony

KW - complexes

KW - main group chemistry

KW - reactivity

KW - stibinidenes

KW - ARSINIDENE

KW - MO

KW - ANTIMONY(I)

KW - LIGAND

KW - CR

KW - SB

UR - http://www.scopus.com/inward/record.url?scp=85125042512&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/c1c968dc-a8ee-34e5-b9b8-d938dca7899c/

U2 - 10.1002/zaac.202200014

DO - 10.1002/zaac.202200014

M3 - Article

AN - SCOPUS:85125042512

VL - 648

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 13

M1 - e202200014

ER -

ID: 93941093