Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Stibinidene complexes are rare and highly sensitive low-valent main group compounds, which have not been studied extensively for their reaction behavior so far. In the reaction with GaCl3, the stibinidene complex [ClSb{Cr(CO)5}2(thf)] (1) shows a dimerization to [ClSb{Cr(CO)5}2]2 (2) and yields the anionic double-chlorinated compound [Cl2Sb{Cr(CO)5}2]− (3) in the reaction with different ionic nucleophiles. When using neutral nucleophiles (such as amines, isocyanides and phosphines) as reaction partners, tetrahedral complexes of the type [ClSb{Cr(CO)5}2Nu] (4: Nu=NH2Mes; 5: Nu=CN(dmp); 6: Nu=PPh3; 7: Nu=PPh2H) are formed which can be used in subsequent reactions. All of these products are among the first of their type to be synthesized and isolated.
Язык оригинала | английский |
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Номер статьи | e202200014 |
Число страниц | 9 |
Журнал | Zeitschrift fur Anorganische und Allgemeine Chemie |
Том | 648 |
Номер выпуска | 13 |
Дата раннего онлайн-доступа | 11 фев 2022 |
DOI | |
Состояние | Опубликовано - 14 июл 2022 |
ID: 93941093