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Reactions of N,3-diarylpropiolamides with arenes under superelectrophilic activation : Synthesis of 4,4-diaryl-3,4-dihydroquinolin-2(1H)-ones and their derivatives. / Gurskaya, Larisa Yu; Belyanskaya, Diana S.; Ryabukhin, Dmitry S.; Nilov, Denis I.; Boyarskaya, Irina A.; Vasilyev, Aleksander V.

в: Beilstein Journal of Organic Chemistry, Том 12, 11.05.2016, стр. 950-956.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Gurskaya, LY, Belyanskaya, DS, Ryabukhin, DS, Nilov, DI, Boyarskaya, IA & Vasilyev, AV 2016, 'Reactions of N,3-diarylpropiolamides with arenes under superelectrophilic activation: Synthesis of 4,4-diaryl-3,4-dihydroquinolin-2(1H)-ones and their derivatives', Beilstein Journal of Organic Chemistry, Том. 12, стр. 950-956. https://doi.org/10.3762/bjoc.12.93

APA

Gurskaya, L. Y., Belyanskaya, D. S., Ryabukhin, D. S., Nilov, D. I., Boyarskaya, I. A., & Vasilyev, A. V. (2016). Reactions of N,3-diarylpropiolamides with arenes under superelectrophilic activation: Synthesis of 4,4-diaryl-3,4-dihydroquinolin-2(1H)-ones and their derivatives. Beilstein Journal of Organic Chemistry, 12, 950-956. https://doi.org/10.3762/bjoc.12.93

Vancouver

Gurskaya LY, Belyanskaya DS, Ryabukhin DS, Nilov DI, Boyarskaya IA, Vasilyev AV. Reactions of N,3-diarylpropiolamides with arenes under superelectrophilic activation: Synthesis of 4,4-diaryl-3,4-dihydroquinolin-2(1H)-ones and their derivatives. Beilstein Journal of Organic Chemistry. 2016 Май 11;12:950-956. https://doi.org/10.3762/bjoc.12.93

Author

Gurskaya, Larisa Yu ; Belyanskaya, Diana S. ; Ryabukhin, Dmitry S. ; Nilov, Denis I. ; Boyarskaya, Irina A. ; Vasilyev, Aleksander V. / Reactions of N,3-diarylpropiolamides with arenes under superelectrophilic activation : Synthesis of 4,4-diaryl-3,4-dihydroquinolin-2(1H)-ones and their derivatives. в: Beilstein Journal of Organic Chemistry. 2016 ; Том 12. стр. 950-956.

BibTeX

@article{6d7b299e5af243cf9dcec702e27e8175,
title = "Reactions of N,3-diarylpropiolamides with arenes under superelectrophilic activation: Synthesis of 4,4-diaryl-3,4-dihydroquinolin-2(1H)-ones and their derivatives",
abstract = "The reaction of 3-aryl-N-(aryl)propiolamides with arenes in TfOH at room temperature for 0.5 h led to 4,4-diaryl-3,4-dihydroquinolin-2-(1H)-ones in yields of 44-98%. The obtained dihydroquinolinones were further transformed into the corresponding N-acyl or N-formyl derivatives. For the latter, the superelectrophilic activation of the N-formyl group by TfOH in the reaction with benzene resulted in the formation of N-(diphenylmethyl)-substituted dihydroquinolinones.",
keywords = "Alkynes, Friedel-Crafts reactions, Quinolinones, Superacids, Superelectrophilic activation",
author = "Gurskaya, {Larisa Yu} and Belyanskaya, {Diana S.} and Ryabukhin, {Dmitry S.} and Nilov, {Denis I.} and Boyarskaya, {Irina A.} and Vasilyev, {Aleksander V.}",
note = "Publisher Copyright: {\textcopyright} 2016 Gurskaya et al; licensee Beilstein-Institut. Copyright: Copyright 2016 Elsevier B.V., All rights reserved.",
year = "2016",
month = may,
day = "11",
doi = "10.3762/bjoc.12.93",
language = "English",
volume = "12",
pages = "950--956",
journal = "Beilstein Journal of Organic Chemistry",
issn = "1860-5397",
publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",

}

RIS

TY - JOUR

T1 - Reactions of N,3-diarylpropiolamides with arenes under superelectrophilic activation

T2 - Synthesis of 4,4-diaryl-3,4-dihydroquinolin-2(1H)-ones and their derivatives

AU - Gurskaya, Larisa Yu

AU - Belyanskaya, Diana S.

AU - Ryabukhin, Dmitry S.

AU - Nilov, Denis I.

AU - Boyarskaya, Irina A.

AU - Vasilyev, Aleksander V.

N1 - Publisher Copyright: © 2016 Gurskaya et al; licensee Beilstein-Institut. Copyright: Copyright 2016 Elsevier B.V., All rights reserved.

PY - 2016/5/11

Y1 - 2016/5/11

N2 - The reaction of 3-aryl-N-(aryl)propiolamides with arenes in TfOH at room temperature for 0.5 h led to 4,4-diaryl-3,4-dihydroquinolin-2-(1H)-ones in yields of 44-98%. The obtained dihydroquinolinones were further transformed into the corresponding N-acyl or N-formyl derivatives. For the latter, the superelectrophilic activation of the N-formyl group by TfOH in the reaction with benzene resulted in the formation of N-(diphenylmethyl)-substituted dihydroquinolinones.

AB - The reaction of 3-aryl-N-(aryl)propiolamides with arenes in TfOH at room temperature for 0.5 h led to 4,4-diaryl-3,4-dihydroquinolin-2-(1H)-ones in yields of 44-98%. The obtained dihydroquinolinones were further transformed into the corresponding N-acyl or N-formyl derivatives. For the latter, the superelectrophilic activation of the N-formyl group by TfOH in the reaction with benzene resulted in the formation of N-(diphenylmethyl)-substituted dihydroquinolinones.

KW - Alkynes

KW - Friedel-Crafts reactions

KW - Quinolinones

KW - Superacids

KW - Superelectrophilic activation

UR - http://www.scopus.com/inward/record.url?scp=84976413214&partnerID=8YFLogxK

U2 - 10.3762/bjoc.12.93

DO - 10.3762/bjoc.12.93

M3 - Article

VL - 12

SP - 950

EP - 956

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 1860-5397

ER -

ID: 7576360