Reaction of In(C6F5)3Et2O with Complexes of Copper and Silver Monochlorides with N,N′-Bis(isopropylphenyl)imidazol-2-ylidene

Standard

Reaction of In(C₆F₅)₃Et₂O with Complexes of Copper and Silver Monochlorides with N,N′-Bis(isopropylphenyl)imidazol-2-ylidene. / Shcherbina, N. A.; Kazakov, I. V.; Spiridonova, D. V.; Suslonov, V. V.; Khoroshilova, O. V.; Mikhailov, V. N.; Timoshkin, A. Y.

в: Russian Journal of General Chemistry, Том 90, № 12, 12.2020, стр. 2503-2508.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Author

Shcherbina, N. A. ; Kazakov, I. V. ; Spiridonova, D. V. ; Suslonov, V. V. ; Khoroshilova, O. V. ; Mikhailov, V. N. ; Timoshkin, A. Y. / Reaction of In(C₆F₅)₃Et₂O with Complexes of Copper and Silver Monochlorides with N,N′-Bis(isopropylphenyl)imidazol-2-ylidene. в: Russian Journal of General Chemistry. 2020 ; Том 90, № 12. стр. 2503-2508.

BibTeX

@article{ab0f68444c394ceb93edcbb59f40cff6,

title = "Reaction of In(C6F5)3Et2O with Complexes of Copper and Silver Monochlorides with N,N′-Bis(isopropylphenyl)imidazol-2-ylidene",

abstract = "Abstract: The reaction of In(C6F5)3·Et2O with NHCdipp·CuCl and NHCdipp·AgCl in dichloromethane at room temperature leads to the formation of the complex [(NHCdipp)Cu(μ-Cl)2In(C6F5)2] and the solvate [(NHCdipp)2Ag]+· [In2(μ-Cl)(C6F5)6]–·СH2Cl2 [NHCdipp—N,N′-bis(isopropylphenyl)imidazol-2-ylidene]. Structures of the obtained compounds were determined by the single crystal X-ray diffraction analysis. An increase in Lewis acidity due to the introduction of electronegative C6F5 groups makes it possible to stabilize the binuclear anion [In2(μ-Cl)(C6F5)6]–.",

keywords = "copper(I) chloride, N-heterocyclic carbene, silver(I) chloride, tris(pentafluorophenyl)indium",

author = "Shcherbina, {N. A.} and Kazakov, {I. V.} and Spiridonova, {D. V.} and Suslonov, {V. V.} and Khoroshilova, {O. V.} and Mikhailov, {V. N.} and Timoshkin, {A. Y.}",

note = "Funding Information: The work was carried out with the financial support of the Russian Science Foundation (grant no. 18-13-00196) using the equipment of the Resource Centers “Magnetic Resonance Research methods” and “X-ray Diffraction Research methods” of St. Petersburg State University. Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2020",

month = dec,

doi = "10.1134/S1070363220120440",

language = "English",

volume = "90",

pages = "2503--2508",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "12",

}

RIS

TY - JOUR

T1 - Reaction of In(C6F5)3Et2O with Complexes of Copper and Silver Monochlorides with N,N′-Bis(isopropylphenyl)imidazol-2-ylidene

AU - Shcherbina, N. A.

AU - Kazakov, I. V.

AU - Spiridonova, D. V.

AU - Suslonov, V. V.

AU - Khoroshilova, O. V.

AU - Mikhailov, V. N.

AU - Timoshkin, A. Y.

N1 - Funding Information: The work was carried out with the financial support of the Russian Science Foundation (grant no. 18-13-00196) using the equipment of the Resource Centers “Magnetic Resonance Research methods” and “X-ray Diffraction Research methods” of St. Petersburg State University. Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - Abstract: The reaction of In(C6F5)3·Et2O with NHCdipp·CuCl and NHCdipp·AgCl in dichloromethane at room temperature leads to the formation of the complex [(NHCdipp)Cu(μ-Cl)2In(C6F5)2] and the solvate [(NHCdipp)2Ag]+· [In2(μ-Cl)(C6F5)6]–·СH2Cl2 [NHCdipp—N,N′-bis(isopropylphenyl)imidazol-2-ylidene]. Structures of the obtained compounds were determined by the single crystal X-ray diffraction analysis. An increase in Lewis acidity due to the introduction of electronegative C6F5 groups makes it possible to stabilize the binuclear anion [In2(μ-Cl)(C6F5)6]–.

AB - Abstract: The reaction of In(C6F5)3·Et2O with NHCdipp·CuCl and NHCdipp·AgCl in dichloromethane at room temperature leads to the formation of the complex [(NHCdipp)Cu(μ-Cl)2In(C6F5)2] and the solvate [(NHCdipp)2Ag]+· [In2(μ-Cl)(C6F5)6]–·СH2Cl2 [NHCdipp—N,N′-bis(isopropylphenyl)imidazol-2-ylidene]. Structures of the obtained compounds were determined by the single crystal X-ray diffraction analysis. An increase in Lewis acidity due to the introduction of electronegative C6F5 groups makes it possible to stabilize the binuclear anion [In2(μ-Cl)(C6F5)6]–.

KW - copper(I) chloride

KW - N-heterocyclic carbene

KW - silver(I) chloride

KW - tris(pentafluorophenyl)indium

UR - http://www.scopus.com/inward/record.url?scp=85100565905&partnerID=8YFLogxK

U2 - 10.1134/S1070363220120440

DO - 10.1134/S1070363220120440

M3 - Article

AN - SCOPUS:85100565905

VL - 90

SP - 2503

EP - 2508

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 12

ER -

ID: 74538236