Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes. / Strelnik, Igor D.; Musina, Elvira I.; Ignatieva, Svetlana N.; Balueva, Anna S.; Gerasimova, Tatiana P.; Katsyuba, Sergey A.; Krivolapov, Dmitry B.; Dobrynin, Alexey B.; Bannwarth, Christoph; Grimme, Stefan; Kolesnikov, Ilya E.; Karasik, Andrey A.; Sinyashin, Oleg G.
в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 643, № 14, 03.08.2017, стр. 895-902.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes
AU - Strelnik, Igor D.
AU - Musina, Elvira I.
AU - Ignatieva, Svetlana N.
AU - Balueva, Anna S.
AU - Gerasimova, Tatiana P.
AU - Katsyuba, Sergey A.
AU - Krivolapov, Dmitry B.
AU - Dobrynin, Alexey B.
AU - Bannwarth, Christoph
AU - Grimme, Stefan
AU - Kolesnikov, Ilya E.
AU - Karasik, Andrey A.
AU - Sinyashin, Oleg G.
PY - 2017/8/3
Y1 - 2017/8/3
N2 - 1,5-bis(R)-3,7-bis[2-(pyridine-2′-yl)ethyl)-1,5-diaza-3,7-diphosphacyclooctanes 1 and 2 and their copper(I) complexes 3 and 4 were developed. The butterfly-shaped copper-iodide core and unusual P,N-chelate and P,P-bridged coordination mode of the heterocyclic ligand in the dinuclear complexes 3 and 4 were revealed. Complexes 3 and 4 display emission in green range of spectra, with lifetimes in a microsecond domain and quantum yields of luminescence in solid-state up to 38 %. Thermochromic effects found for the phosphorescence of 4 in solutions are ascribed to rigidochromism.
AB - 1,5-bis(R)-3,7-bis[2-(pyridine-2′-yl)ethyl)-1,5-diaza-3,7-diphosphacyclooctanes 1 and 2 and their copper(I) complexes 3 and 4 were developed. The butterfly-shaped copper-iodide core and unusual P,N-chelate and P,P-bridged coordination mode of the heterocyclic ligand in the dinuclear complexes 3 and 4 were revealed. Complexes 3 and 4 display emission in green range of spectra, with lifetimes in a microsecond domain and quantum yields of luminescence in solid-state up to 38 %. Thermochromic effects found for the phosphorescence of 4 in solutions are ascribed to rigidochromism.
KW - Aminomethylphosphines
KW - Copper
KW - Functionalized phosphines
KW - Luminescence
KW - P,N-ligands
UR - http://www.scopus.com/inward/record.url?scp=85019179276&partnerID=8YFLogxK
U2 - 10.1002/zaac.201700049
DO - 10.1002/zaac.201700049
M3 - Article
AN - SCOPUS:85019179276
VL - 643
SP - 895
EP - 902
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
SN - 0044-2313
IS - 14
ER -
ID: 36096525