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Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes. / Strelnik, Igor D.; Musina, Elvira I.; Ignatieva, Svetlana N.; Balueva, Anna S.; Gerasimova, Tatiana P.; Katsyuba, Sergey A.; Krivolapov, Dmitry B.; Dobrynin, Alexey B.; Bannwarth, Christoph; Grimme, Stefan; Kolesnikov, Ilya E.; Karasik, Andrey A.; Sinyashin, Oleg G.
In:
Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 643, No. 14, 03.08.2017, p. 895-902.
Research output: Contribution to journal › Article › peer-review
Harvard
Strelnik, ID, Musina, EI, Ignatieva, SN, Balueva, AS, Gerasimova, TP, Katsyuba, SA, Krivolapov, DB, Dobrynin, AB, Bannwarth, C, Grimme, S
, Kolesnikov, IE, Karasik, AA & Sinyashin, OG 2017, '
Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes',
Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 643, no. 14, pp. 895-902.
https://doi.org/10.1002/zaac.201700049APA
Strelnik, I. D., Musina, E. I., Ignatieva, S. N., Balueva, A. S., Gerasimova, T. P., Katsyuba, S. A., Krivolapov, D. B., Dobrynin, A. B., Bannwarth, C., Grimme, S.
, Kolesnikov, I. E., Karasik, A. A., & Sinyashin, O. G. (2017).
Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes.
Zeitschrift fur Anorganische und Allgemeine Chemie,
643(14), 895-902.
https://doi.org/10.1002/zaac.201700049Vancouver
Author
Strelnik, Igor D. ; Musina, Elvira I. ; Ignatieva, Svetlana N. ; Balueva, Anna S. ; Gerasimova, Tatiana P. ; Katsyuba, Sergey A. ; Krivolapov, Dmitry B. ; Dobrynin, Alexey B. ; Bannwarth, Christoph ; Grimme, Stefan
; Kolesnikov, Ilya E. ; Karasik, Andrey A. ; Sinyashin, Oleg G. /
Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes. In:
Zeitschrift fur Anorganische und Allgemeine Chemie. 2017 ; Vol. 643, No. 14. pp. 895-902.
BibTeX
@article{c84bd77af557484e9f0f112cf69fbe9a,
title = "Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes",
abstract = "1,5-bis(R)-3,7-bis[2-(pyridine-2′-yl)ethyl)-1,5-diaza-3,7-diphosphacyclooctanes 1 and 2 and their copper(I) complexes 3 and 4 were developed. The butterfly-shaped copper-iodide core and unusual P,N-chelate and P,P-bridged coordination mode of the heterocyclic ligand in the dinuclear complexes 3 and 4 were revealed. Complexes 3 and 4 display emission in green range of spectra, with lifetimes in a microsecond domain and quantum yields of luminescence in solid-state up to 38 %. Thermochromic effects found for the phosphorescence of 4 in solutions are ascribed to rigidochromism.",
keywords = "Aminomethylphosphines, Copper, Functionalized phosphines, Luminescence, P,N-ligands",
author = "Strelnik, {Igor D.} and Musina, {Elvira I.} and Ignatieva, {Svetlana N.} and Balueva, {Anna S.} and Gerasimova, {Tatiana P.} and Katsyuba, {Sergey A.} and Krivolapov, {Dmitry B.} and Dobrynin, {Alexey B.} and Christoph Bannwarth and Stefan Grimme and Kolesnikov, {Ilya E.} and Karasik, {Andrey A.} and Sinyashin, {Oleg G.}",
year = "2017",
month = aug,
day = "3",
doi = "10.1002/zaac.201700049",
language = "English",
volume = "643",
pages = "895--902",
journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",
issn = "0044-2313",
publisher = "Wiley-Blackwell",
number = "14",
}
RIS
TY - JOUR
T1 - Pyridyl Containing 1,5-Diaza-3,7-diphosphacyclooctanes as Bridging Ligands for Dinuclear Copper(I) Complexes
AU - Strelnik, Igor D.
AU - Musina, Elvira I.
AU - Ignatieva, Svetlana N.
AU - Balueva, Anna S.
AU - Gerasimova, Tatiana P.
AU - Katsyuba, Sergey A.
AU - Krivolapov, Dmitry B.
AU - Dobrynin, Alexey B.
AU - Bannwarth, Christoph
AU - Grimme, Stefan
AU - Kolesnikov, Ilya E.
AU - Karasik, Andrey A.
AU - Sinyashin, Oleg G.
PY - 2017/8/3
Y1 - 2017/8/3
N2 - 1,5-bis(R)-3,7-bis[2-(pyridine-2′-yl)ethyl)-1,5-diaza-3,7-diphosphacyclooctanes 1 and 2 and their copper(I) complexes 3 and 4 were developed. The butterfly-shaped copper-iodide core and unusual P,N-chelate and P,P-bridged coordination mode of the heterocyclic ligand in the dinuclear complexes 3 and 4 were revealed. Complexes 3 and 4 display emission in green range of spectra, with lifetimes in a microsecond domain and quantum yields of luminescence in solid-state up to 38 %. Thermochromic effects found for the phosphorescence of 4 in solutions are ascribed to rigidochromism.
AB - 1,5-bis(R)-3,7-bis[2-(pyridine-2′-yl)ethyl)-1,5-diaza-3,7-diphosphacyclooctanes 1 and 2 and their copper(I) complexes 3 and 4 were developed. The butterfly-shaped copper-iodide core and unusual P,N-chelate and P,P-bridged coordination mode of the heterocyclic ligand in the dinuclear complexes 3 and 4 were revealed. Complexes 3 and 4 display emission in green range of spectra, with lifetimes in a microsecond domain and quantum yields of luminescence in solid-state up to 38 %. Thermochromic effects found for the phosphorescence of 4 in solutions are ascribed to rigidochromism.
KW - Aminomethylphosphines
KW - Copper
KW - Functionalized phosphines
KW - Luminescence
KW - P,N-ligands
UR - http://www.scopus.com/inward/record.url?scp=85019179276&partnerID=8YFLogxK
U2 - 10.1002/zaac.201700049
DO - 10.1002/zaac.201700049
M3 - Article
AN - SCOPUS:85019179276
VL - 643
SP - 895
EP - 902
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
SN - 0044-2313
IS - 14
ER -
