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Protonated member of poly(diallylammonium) family : Hydrodynamic and conformational properties. / Yevlampieva, Natalia; Vezo, Olga; Simonova, Yulia; Timofeeva, Larisa.

в: International Journal of Polymer Analysis and Characterization, Том 23, № 5, 2018, стр. 403-414.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Yevlampieva, N, Vezo, O, Simonova, Y & Timofeeva, L 2018, 'Protonated member of poly(diallylammonium) family: Hydrodynamic and conformational properties', International Journal of Polymer Analysis and Characterization, Том. 23, № 5, стр. 403-414. https://doi.org/10.1080/1023666X.2018.1461471

APA

Yevlampieva, N., Vezo, O., Simonova, Y., & Timofeeva, L. (2018). Protonated member of poly(diallylammonium) family: Hydrodynamic and conformational properties. International Journal of Polymer Analysis and Characterization, 23(5), 403-414. https://doi.org/10.1080/1023666X.2018.1461471

Vancouver

Yevlampieva N, Vezo O, Simonova Y, Timofeeva L. Protonated member of poly(diallylammonium) family: Hydrodynamic and conformational properties. International Journal of Polymer Analysis and Characterization. 2018;23(5):403-414. https://doi.org/10.1080/1023666X.2018.1461471

Author

Yevlampieva, Natalia ; Vezo, Olga ; Simonova, Yulia ; Timofeeva, Larisa. / Protonated member of poly(diallylammonium) family : Hydrodynamic and conformational properties. в: International Journal of Polymer Analysis and Characterization. 2018 ; Том 23, № 5. стр. 403-414.

BibTeX

@article{fcadc70723164d88810098149c801c2a,
title = "Protonated member of poly(diallylammonium) family: Hydrodynamic and conformational properties",
abstract = "Secondary polyamine in protonated salt form - poly(diallylammonium trifluoro-acetate) is characterized as representative of polymer series based on N,N-diallyl-ammonium. Its hydrodynamic behavior in 1M NaCl has been compared with the other series members - quaternary poly(diallyldimethylammonium chloride) and tertiary poly(diallylmethylammonium trifluoroacetate). It was shown that these polymers belong to semirigid class whose Kuhn segment length approximate to 4nm just slightly depends on chemical structure at high ionic strength. As specific for secondary polyamine, the sensitivity to proton equilibrium in solution and counter ion type was detected resulting in great difference of its Mark-Kuhn-Houwink equations from the quaternary analogue at the same conditions.",
keywords = "Cationic polyelectrolytes, poly(diallylammonium) salts, hydrodynamic behavior, structure-property relations, MOLECULAR-WEIGHT POLYMERS, DIALLYLDIMETHYLAMMONIUM CHLORIDE, POLYELECTROLYTE SOLUTIONS, RADICAL POLYMERIZATION, MALEIC-ACID, COPOLYMERS, CONTINUUM, HYDRATION, ANIONS",
author = "Natalia Yevlampieva and Olga Vezo and Yulia Simonova and Larisa Timofeeva",
year = "2018",
doi = "10.1080/1023666X.2018.1461471",
language = "Английский",
volume = "23",
pages = "403--414",
journal = "International Journal of Polymer Analysis and Characterization",
issn = "1023-666X",
publisher = "Taylor & Francis",
number = "5",

}

RIS

TY - JOUR

T1 - Protonated member of poly(diallylammonium) family

T2 - Hydrodynamic and conformational properties

AU - Yevlampieva, Natalia

AU - Vezo, Olga

AU - Simonova, Yulia

AU - Timofeeva, Larisa

PY - 2018

Y1 - 2018

N2 - Secondary polyamine in protonated salt form - poly(diallylammonium trifluoro-acetate) is characterized as representative of polymer series based on N,N-diallyl-ammonium. Its hydrodynamic behavior in 1M NaCl has been compared with the other series members - quaternary poly(diallyldimethylammonium chloride) and tertiary poly(diallylmethylammonium trifluoroacetate). It was shown that these polymers belong to semirigid class whose Kuhn segment length approximate to 4nm just slightly depends on chemical structure at high ionic strength. As specific for secondary polyamine, the sensitivity to proton equilibrium in solution and counter ion type was detected resulting in great difference of its Mark-Kuhn-Houwink equations from the quaternary analogue at the same conditions.

AB - Secondary polyamine in protonated salt form - poly(diallylammonium trifluoro-acetate) is characterized as representative of polymer series based on N,N-diallyl-ammonium. Its hydrodynamic behavior in 1M NaCl has been compared with the other series members - quaternary poly(diallyldimethylammonium chloride) and tertiary poly(diallylmethylammonium trifluoroacetate). It was shown that these polymers belong to semirigid class whose Kuhn segment length approximate to 4nm just slightly depends on chemical structure at high ionic strength. As specific for secondary polyamine, the sensitivity to proton equilibrium in solution and counter ion type was detected resulting in great difference of its Mark-Kuhn-Houwink equations from the quaternary analogue at the same conditions.

KW - Cationic polyelectrolytes

KW - poly(diallylammonium) salts

KW - hydrodynamic behavior

KW - structure-property relations

KW - MOLECULAR-WEIGHT POLYMERS

KW - DIALLYLDIMETHYLAMMONIUM CHLORIDE

KW - POLYELECTROLYTE SOLUTIONS

KW - RADICAL POLYMERIZATION

KW - MALEIC-ACID

KW - COPOLYMERS

KW - CONTINUUM

KW - HYDRATION

KW - ANIONS

U2 - 10.1080/1023666X.2018.1461471

DO - 10.1080/1023666X.2018.1461471

M3 - статья

VL - 23

SP - 403

EP - 414

JO - International Journal of Polymer Analysis and Characterization

JF - International Journal of Polymer Analysis and Characterization

SN - 1023-666X

IS - 5

ER -

ID: 37251930