Research output: Contribution to journal › Article › peer-review
Protonated member of poly(diallylammonium) family : Hydrodynamic and conformational properties. / Yevlampieva, Natalia; Vezo, Olga; Simonova, Yulia; Timofeeva, Larisa.
In: International Journal of Polymer Analysis and Characterization, Vol. 23, No. 5, 2018, p. 403-414.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Protonated member of poly(diallylammonium) family
T2 - Hydrodynamic and conformational properties
AU - Yevlampieva, Natalia
AU - Vezo, Olga
AU - Simonova, Yulia
AU - Timofeeva, Larisa
PY - 2018
Y1 - 2018
N2 - Secondary polyamine in protonated salt form - poly(diallylammonium trifluoro-acetate) is characterized as representative of polymer series based on N,N-diallyl-ammonium. Its hydrodynamic behavior in 1M NaCl has been compared with the other series members - quaternary poly(diallyldimethylammonium chloride) and tertiary poly(diallylmethylammonium trifluoroacetate). It was shown that these polymers belong to semirigid class whose Kuhn segment length approximate to 4nm just slightly depends on chemical structure at high ionic strength. As specific for secondary polyamine, the sensitivity to proton equilibrium in solution and counter ion type was detected resulting in great difference of its Mark-Kuhn-Houwink equations from the quaternary analogue at the same conditions.
AB - Secondary polyamine in protonated salt form - poly(diallylammonium trifluoro-acetate) is characterized as representative of polymer series based on N,N-diallyl-ammonium. Its hydrodynamic behavior in 1M NaCl has been compared with the other series members - quaternary poly(diallyldimethylammonium chloride) and tertiary poly(diallylmethylammonium trifluoroacetate). It was shown that these polymers belong to semirigid class whose Kuhn segment length approximate to 4nm just slightly depends on chemical structure at high ionic strength. As specific for secondary polyamine, the sensitivity to proton equilibrium in solution and counter ion type was detected resulting in great difference of its Mark-Kuhn-Houwink equations from the quaternary analogue at the same conditions.
KW - Cationic polyelectrolytes
KW - poly(diallylammonium) salts
KW - hydrodynamic behavior
KW - structure-property relations
KW - MOLECULAR-WEIGHT POLYMERS
KW - DIALLYLDIMETHYLAMMONIUM CHLORIDE
KW - POLYELECTROLYTE SOLUTIONS
KW - RADICAL POLYMERIZATION
KW - MALEIC-ACID
KW - COPOLYMERS
KW - CONTINUUM
KW - HYDRATION
KW - ANIONS
U2 - 10.1080/1023666X.2018.1461471
DO - 10.1080/1023666X.2018.1461471
M3 - статья
VL - 23
SP - 403
EP - 414
JO - International Journal of Polymer Analysis and Characterization
JF - International Journal of Polymer Analysis and Characterization
SN - 1023-666X
IS - 5
ER -
ID: 37251930