DOI

The validity of the assumption on the predominant contribution of the stepwise processes to the ionic micelle formation/destruction in the vicinity of critical micelle concentration was investigated by molecular dynamics simulation. A coarse-grained model was used to describe the surfactant/water mixture. The cluster size distribution was estimated directly from molecular dynamics simulations or obtained from a reduced set of kinetic equations. The good agreement between two approaches shows that the neglect of the terms responsible for cluster fusion/fission is fully justified and that such processes are less important than stepwise aggregation.

Язык оригиналаанглийский
Страницы (с-по)10715-10720
Число страниц6
ЖурналJournal of Physical Chemistry B
Том113
Номер выпуска31
DOI
СостояниеОпубликовано - 6 авг 2009

    Предметные области Scopus

  • Поверхности, слои и пленки
  • Физическая и теоретическая химия
  • Химия материалов

ID: 9442352