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The validity of the assumption on the predominant contribution of the stepwise processes to the ionic micelle formation/destruction in the vicinity of critical micelle concentration was investigated by molecular dynamics simulation. A coarse-grained model was used to describe the surfactant/water mixture. The cluster size distribution was estimated directly from molecular dynamics simulations or obtained from a reduced set of kinetic equations. The good agreement between two approaches shows that the neglect of the terms responsible for cluster fusion/fission is fully justified and that such processes are less important than stepwise aggregation.
Original language | English |
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Pages (from-to) | 10715-10720 |
Number of pages | 6 |
Journal | Journal of Physical Chemistry B |
Volume | 113 |
Issue number | 31 |
DOIs | |
State | Published - 6 Aug 2009 |
ID: 9442352