TY - JOUR

T1 - POLYMERIZATION OF ACRYLIC MONOMERS WITH DENDRONS BASED ON DICARBOXYLIC Α-AMINO ACID UNITS

AU - Girbasova, N.V.

AU - Migunova, I.I.

AU - Raspopova, I.R.

AU - Bilibin, A.Yu.

PY - 2003

Y1 - 2003

N2 - A series of acrylic monomers carrying dendrons based on aspartic and glutamic acids of various generations was synthesized. The free-radical polymerization of the synthesized monomers with the use of material and radiation-chemical initiation was studied. It was shown that monomers carrying dendrons of the first and second generations undergo polymerization to afford products with high polymerization degrees; as the generation number of the dendrons increases, the polymerization degree of the products sharply decreases. The monomer bearing the third-generation dendron yields an oligomer only under the radiation-induced polymerization conditions. The hydrolysis of the terminal methoxycarbonyl groups of dendritic polymers was accomplished, and the polyelectrolyte effect was discovered in solutions of the products obtained.

AB - A series of acrylic monomers carrying dendrons based on aspartic and glutamic acids of various generations was synthesized. The free-radical polymerization of the synthesized monomers with the use of material and radiation-chemical initiation was studied. It was shown that monomers carrying dendrons of the first and second generations undergo polymerization to afford products with high polymerization degrees; as the generation number of the dendrons increases, the polymerization degree of the products sharply decreases. The monomer bearing the third-generation dendron yields an oligomer only under the radiation-induced polymerization conditions. The hydrolysis of the terminal methoxycarbonyl groups of dendritic polymers was accomplished, and the polyelectrolyte effect was discovered in solutions of the products obtained.

M3 - Article

SP - 320

EP - 329

JO - Polymer Science - Series A

JF - Polymer Science - Series A

SN - 0965-545X

IS - 4

ER -