Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Polar and electrooptical properties of [60]fullerene-containing poly(benzyl ether) dendrimers in solution. / Scanu, David; Yevlampieva, Natalia P.; Deschenaux, Robert.
в: Macromolecules, Том 40, № 4, 20.02.2007, стр. 1133-1139.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Polar and electrooptical properties of [60]fullerene-containing poly(benzyl ether) dendrimers in solution
AU - Scanu, David
AU - Yevlampieva, Natalia P.
AU - Deschenaux, Robert
PY - 2007/2/20
Y1 - 2007/2/20
N2 - [60]Fulleropyrrolidine-containing poly(benzyl ether) dendrimers 1-4 were synthesized via 1,3-dipolar cycloaddition of amino acid and aldehyde derivatives and [60]fullerene. Their dielectric and electrooptical (Kerr effect) solution properties were studied and compared with poly(propyleneimine) dendrimers, namely DAB-dendr-(alkyl chain)n and DAB-dendr-(CN)n, and with known symmetrical and non-symmetrical poly(benzyl ether) dendrimers carrying benzyl groups ([Gx]-[C]-[Gx]) or benzyl and cyanobenzyl groups (CNn-[Gx]-[C]-[Gx+1]), respectively. It was shown that 1-4 display similar polar and electrooptical characteristics independent of their dendrimer generation. This is in contrast to the reference dendrimers for which a strong dependence of total dipole moment on dendrimer generation was observed.
AB - [60]Fulleropyrrolidine-containing poly(benzyl ether) dendrimers 1-4 were synthesized via 1,3-dipolar cycloaddition of amino acid and aldehyde derivatives and [60]fullerene. Their dielectric and electrooptical (Kerr effect) solution properties were studied and compared with poly(propyleneimine) dendrimers, namely DAB-dendr-(alkyl chain)n and DAB-dendr-(CN)n, and with known symmetrical and non-symmetrical poly(benzyl ether) dendrimers carrying benzyl groups ([Gx]-[C]-[Gx]) or benzyl and cyanobenzyl groups (CNn-[Gx]-[C]-[Gx+1]), respectively. It was shown that 1-4 display similar polar and electrooptical characteristics independent of their dendrimer generation. This is in contrast to the reference dendrimers for which a strong dependence of total dipole moment on dendrimer generation was observed.
UR - http://www.scopus.com/inward/record.url?scp=33847746337&partnerID=8YFLogxK
U2 - 10.1021/ma061795i
DO - 10.1021/ma061795i
M3 - Article
AN - SCOPUS:33847746337
VL - 40
SP - 1133
EP - 1139
JO - Macromolecules
JF - Macromolecules
SN - 0024-9297
IS - 4
ER -
ID: 37393015