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Polar and electrooptical properties of [60]fullerene-containing poly(benzyl ether) dendrimers in solution. / Scanu, David; Yevlampieva, Natalia P.; Deschenaux, Robert.

In: Macromolecules, Vol. 40, No. 4, 20.02.2007, p. 1133-1139.

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Scanu, David ; Yevlampieva, Natalia P. ; Deschenaux, Robert. / Polar and electrooptical properties of [60]fullerene-containing poly(benzyl ether) dendrimers in solution. In: Macromolecules. 2007 ; Vol. 40, No. 4. pp. 1133-1139.

BibTeX

@article{54dd7e5a39d545d9b6893cdd598d9555,
title = "Polar and electrooptical properties of [60]fullerene-containing poly(benzyl ether) dendrimers in solution",
abstract = "[60]Fulleropyrrolidine-containing poly(benzyl ether) dendrimers 1-4 were synthesized via 1,3-dipolar cycloaddition of amino acid and aldehyde derivatives and [60]fullerene. Their dielectric and electrooptical (Kerr effect) solution properties were studied and compared with poly(propyleneimine) dendrimers, namely DAB-dendr-(alkyl chain)n and DAB-dendr-(CN)n, and with known symmetrical and non-symmetrical poly(benzyl ether) dendrimers carrying benzyl groups ([Gx]-[C]-[Gx]) or benzyl and cyanobenzyl groups (CNn-[Gx]-[C]-[Gx+1]), respectively. It was shown that 1-4 display similar polar and electrooptical characteristics independent of their dendrimer generation. This is in contrast to the reference dendrimers for which a strong dependence of total dipole moment on dendrimer generation was observed.",
author = "David Scanu and Yevlampieva, {Natalia P.} and Robert Deschenaux",
year = "2007",
month = feb,
day = "20",
doi = "10.1021/ma061795i",
language = "English",
volume = "40",
pages = "1133--1139",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "4",

}

RIS

TY - JOUR

T1 - Polar and electrooptical properties of [60]fullerene-containing poly(benzyl ether) dendrimers in solution

AU - Scanu, David

AU - Yevlampieva, Natalia P.

AU - Deschenaux, Robert

PY - 2007/2/20

Y1 - 2007/2/20

N2 - [60]Fulleropyrrolidine-containing poly(benzyl ether) dendrimers 1-4 were synthesized via 1,3-dipolar cycloaddition of amino acid and aldehyde derivatives and [60]fullerene. Their dielectric and electrooptical (Kerr effect) solution properties were studied and compared with poly(propyleneimine) dendrimers, namely DAB-dendr-(alkyl chain)n and DAB-dendr-(CN)n, and with known symmetrical and non-symmetrical poly(benzyl ether) dendrimers carrying benzyl groups ([Gx]-[C]-[Gx]) or benzyl and cyanobenzyl groups (CNn-[Gx]-[C]-[Gx+1]), respectively. It was shown that 1-4 display similar polar and electrooptical characteristics independent of their dendrimer generation. This is in contrast to the reference dendrimers for which a strong dependence of total dipole moment on dendrimer generation was observed.

AB - [60]Fulleropyrrolidine-containing poly(benzyl ether) dendrimers 1-4 were synthesized via 1,3-dipolar cycloaddition of amino acid and aldehyde derivatives and [60]fullerene. Their dielectric and electrooptical (Kerr effect) solution properties were studied and compared with poly(propyleneimine) dendrimers, namely DAB-dendr-(alkyl chain)n and DAB-dendr-(CN)n, and with known symmetrical and non-symmetrical poly(benzyl ether) dendrimers carrying benzyl groups ([Gx]-[C]-[Gx]) or benzyl and cyanobenzyl groups (CNn-[Gx]-[C]-[Gx+1]), respectively. It was shown that 1-4 display similar polar and electrooptical characteristics independent of their dendrimer generation. This is in contrast to the reference dendrimers for which a strong dependence of total dipole moment on dendrimer generation was observed.

UR - http://www.scopus.com/inward/record.url?scp=33847746337&partnerID=8YFLogxK

U2 - 10.1021/ma061795i

DO - 10.1021/ma061795i

M3 - Article

AN - SCOPUS:33847746337

VL - 40

SP - 1133

EP - 1139

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 4

ER -

ID: 37393015