Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Paramagnetic complexes of monovalent and trivalent nickel in the catalytic system Ni(COD)2/BF3*OEt2 active in norbornene polymerization. / Kraikivskii, Peter B.; Saraev, Vitaly V.; Bocharova, V. V.; Matveev, D. A.; Petrovskii, S. K.; Gotsko, M. D.
в: Catalysis Communications, Том 12, № 7, 10.03.2011, стр. 634-636.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Paramagnetic complexes of monovalent and trivalent nickel in the catalytic system Ni(COD)2/BF3*OEt2 active in norbornene polymerization
AU - Kraikivskii, Peter B.
AU - Saraev, Vitaly V.
AU - Bocharova, V. V.
AU - Matveev, D. A.
AU - Petrovskii, S. K.
AU - Gotsko, M. D.
PY - 2011/3/10
Y1 - 2011/3/10
N2 - It has been shown that the system Ni(COD)2/BF3? OEt2 may polymerize norbornene with the activity of 1930 kg NB/molNi h. This catalytic system is characterized by minor content of the Lewis acid; the activity peaks at the molar ratio of B:Ni = 5. The norbornene polymerization was first demonstrated to be attended with the formation of trivalent nickel metallocyclic complexes. A monovalent nickel complex was used as a precursor for the active species.
AB - It has been shown that the system Ni(COD)2/BF3? OEt2 may polymerize norbornene with the activity of 1930 kg NB/molNi h. This catalytic system is characterized by minor content of the Lewis acid; the activity peaks at the molar ratio of B:Ni = 5. The norbornene polymerization was first demonstrated to be attended with the formation of trivalent nickel metallocyclic complexes. A monovalent nickel complex was used as a precursor for the active species.
KW - Boron trifluoride
KW - Monovalent nickel
KW - Norbornene
KW - Polymerization
KW - Trivalent nickel
UR - http://www.scopus.com/inward/record.url?scp=78651099218&partnerID=8YFLogxK
U2 - 10.1016/j.catcom.2010.12.016
DO - 10.1016/j.catcom.2010.12.016
M3 - Article
AN - SCOPUS:78651099218
VL - 12
SP - 634
EP - 636
JO - Catalysis Communications
JF - Catalysis Communications
SN - 1566-7367
IS - 7
ER -
ID: 51891612