DOI

  • Peter B. Kraikivskii
  • Vitaly V. Saraev
  • V. V. Bocharova
  • D. A. Matveev
  • S. K. Petrovskii
  • M. D. Gotsko

It has been shown that the system Ni(COD)2/BF3? OEt2 may polymerize norbornene with the activity of 1930 kg NB/molNi h. This catalytic system is characterized by minor content of the Lewis acid; the activity peaks at the molar ratio of B:Ni = 5. The norbornene polymerization was first demonstrated to be attended with the formation of trivalent nickel metallocyclic complexes. A monovalent nickel complex was used as a precursor for the active species.

Язык оригиналаанглийский
Страницы (с-по)634-636
Число страниц3
ЖурналCatalysis Communications
Том12
Номер выпуска7
DOI
СостояниеОпубликовано - 10 мар 2011

    Предметные области Scopus

  • Катализ
  • Химия (все)
  • Химия и технология процессов

ID: 51891612