The exciton luminescence of ZnTe matrices with the embedded CdTe submonolayer inclusions is investigated. It is shown that the exciton localized by CdTe narrow gap component dominates in the emission spectrum. These localized excitons are coupled mainly with the phonons belonging to the cadmium enriched layers. The real distribution of cadmium in the direction of the heterostructure growth is determined from the energy position of the localized exciton emission bands.