Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid. / Назарчук, Евгений Васильевич; Сийдра, Олег Иоханнесович; Чаркин, Дмитрий; Чуканов, Никита В.; Захаров, Александр Ю.; Калмыков, Степан Н.; Ихолайнен, Юрий А.; Шариков, Михаил И.
в: Zeitschfrift fur Kristallographie, Том 234, № 2, 01.02.2019, стр. 109-118.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid
AU - Назарчук, Евгений Васильевич
AU - Сийдра, Олег Иоханнесович
AU - Чаркин, Дмитрий
AU - Чуканов, Никита В.
AU - Захаров, Александр Ю.
AU - Калмыков, Степан Н.
AU - Ихолайнен, Юрий А.
AU - Шариков, Михаил И.
PY - 2019/2/1
Y1 - 2019/2/1
N2 - The reaction of sodium N-morpholine acetate with selenic and sulfuric acid and uranyl nitrate results in the formation of two novel open-framework compounds, |Na(Hmfa)|[(UO 2) 2(SeO 4) 3(H 2O)](H 2O) 2 (NaUSe) and [Na 2(SO 3OH)(Hmfa)]|(UO 2)(SO 4) 2| (NaUS), respectively. Despite identical synthetic procedures, sulfate structure dramatically differs from selenate compound. Their common feature is an open-framework featuring two-dimensional system of channels occupied by protonated morpholino-N-acetic acid species. Coordination of Na atoms is different. In NaUSe, [(UO 2) 2 (SeO 4) 3(H 2O)] 2- layers are pillared by {Na 2O 8(H 2O) 2(Hmfa) 2} complexes to form a microporous framework. In NaUS, UO 7 and SO 4 polyhedra of [(UO 2)(SO 4) 2] 2- chains share common oxygen atoms with Na-centered tetrameric complexes providing a three-dimensional integrity of the structure. Both of the compounds are characterized by IR spectroscopy.
AB - The reaction of sodium N-morpholine acetate with selenic and sulfuric acid and uranyl nitrate results in the formation of two novel open-framework compounds, |Na(Hmfa)|[(UO 2) 2(SeO 4) 3(H 2O)](H 2O) 2 (NaUSe) and [Na 2(SO 3OH)(Hmfa)]|(UO 2)(SO 4) 2| (NaUS), respectively. Despite identical synthetic procedures, sulfate structure dramatically differs from selenate compound. Their common feature is an open-framework featuring two-dimensional system of channels occupied by protonated morpholino-N-acetic acid species. Coordination of Na atoms is different. In NaUSe, [(UO 2) 2 (SeO 4) 3(H 2O)] 2- layers are pillared by {Na 2O 8(H 2O) 2(Hmfa) 2} complexes to form a microporous framework. In NaUS, UO 7 and SO 4 polyhedra of [(UO 2)(SO 4) 2] 2- chains share common oxygen atoms with Na-centered tetrameric complexes providing a three-dimensional integrity of the structure. Both of the compounds are characterized by IR spectroscopy.
KW - open-framework materials
KW - selenates
KW - sulfates
KW - uranium
UR - http://www.scopus.com/inward/record.url?scp=85054410724&partnerID=8YFLogxK
U2 - 10.1515/zkri-2018-2103
DO - 10.1515/zkri-2018-2103
M3 - Article
VL - 234
SP - 109
EP - 118
JO - Zeitschfrift fur Kristallographie
JF - Zeitschfrift fur Kristallographie
SN - 0044-2968
IS - 2
ER -
ID: 34613200