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Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid. / Назарчук, Евгений Васильевич; Сийдра, Олег Иоханнесович; Чаркин, Дмитрий; Чуканов, Никита В.; Захаров, Александр Ю.; Калмыков, Степан Н.; Ихолайнен, Юрий А.; Шариков, Михаил И.

In: Zeitschfrift fur Kristallographie, Vol. 234, No. 2, 01.02.2019, p. 109-118.

Research output: Contribution to journal › Article › peer-review

Harvard

Назарчук, ЕВ, Сийдра, ОИ, Чаркин, Д, Чуканов, НВ, Захаров, АЮ, Калмыков, СН, Ихолайнен, ЮА & Шариков, МИ 2019, 'Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid', Zeitschfrift fur Kristallographie, vol. 234, no. 2, pp. 109-118. https://doi.org/10.1515/zkri-2018-2103

APA

Назарчук, Е. В., Сийдра, О. И., Чаркин, Д., Чуканов, Н. В., Захаров, А. Ю., Калмыков, С. Н., Ихолайнен, Ю. А., & Шариков, М. И. (2019). Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid. Zeitschfrift fur Kristallographie, 234(2), 109-118. https://doi.org/10.1515/zkri-2018-2103

Vancouver

Назарчук ЕВ, Сийдра ОИ, Чаркин Д, Чуканов НВ, Захаров АЮ, Калмыков СН et al. Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid. Zeitschfrift fur Kristallographie. 2019 Feb 1;234(2):109-118. https://doi.org/10.1515/zkri-2018-2103

Author

Назарчук, Евгений Васильевич ; Сийдра, Олег Иоханнесович ; Чаркин, Дмитрий ; Чуканов, Никита В. ; Захаров, Александр Ю. ; Калмыков, Степан Н. ; Ихолайнен, Юрий А. ; Шариков, Михаил И. / Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid. In: Zeitschfrift fur Kristallographie. 2019 ; Vol. 234, No. 2. pp. 109-118.

BibTeX

@article{09947eb975f546caaff9ac2fafaf9413,
title = "Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid",
abstract = "The reaction of sodium N-morpholine acetate with selenic and sulfuric acid and uranyl nitrate results in the formation of two novel open-framework compounds, |Na(Hmfa)|[(UO 2) 2(SeO 4) 3(H 2O)](H 2O) 2 (NaUSe) and [Na 2(SO 3OH)(Hmfa)]|(UO 2)(SO 4) 2| (NaUS), respectively. Despite identical synthetic procedures, sulfate structure dramatically differs from selenate compound. Their common feature is an open-framework featuring two-dimensional system of channels occupied by protonated morpholino-N-acetic acid species. Coordination of Na atoms is different. In NaUSe, [(UO 2) 2 (SeO 4) 3(H 2O)] 2- layers are pillared by {Na 2O 8(H 2O) 2(Hmfa) 2} complexes to form a microporous framework. In NaUS, UO 7 and SO 4 polyhedra of [(UO 2)(SO 4) 2] 2- chains share common oxygen atoms with Na-centered tetrameric complexes providing a three-dimensional integrity of the structure. Both of the compounds are characterized by IR spectroscopy. ",
keywords = "open-framework materials, selenates, sulfates, uranium",
author = "Назарчук, {Евгений Васильевич} and Сийдра, {Олег Иоханнесович} and Дмитрий Чаркин and Чуканов, {Никита В.} and Захаров, {Александр Ю.} and Калмыков, {Степан Н.} and Ихолайнен, {Юрий А.} and Шариков, {Михаил И.}",
year = "2019",
month = feb,
day = "1",
doi = "10.1515/zkri-2018-2103",
language = "English",
volume = "234",
pages = "109--118",
journal = "Zeitschfrift fur Kristallographie",
issn = "0044-2968",
publisher = "De Gruyter",
number = "2",

}

RIS

TY - JOUR

T1 - Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid

AU - Назарчук, Евгений Васильевич

AU - Сийдра, Олег Иоханнесович

AU - Чаркин, Дмитрий

AU - Чуканов, Никита В.

AU - Захаров, Александр Ю.

AU - Калмыков, Степан Н.

AU - Ихолайнен, Юрий А.

AU - Шариков, Михаил И.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - The reaction of sodium N-morpholine acetate with selenic and sulfuric acid and uranyl nitrate results in the formation of two novel open-framework compounds, |Na(Hmfa)|[(UO 2) 2(SeO 4) 3(H 2O)](H 2O) 2 (NaUSe) and [Na 2(SO 3OH)(Hmfa)]|(UO 2)(SO 4) 2| (NaUS), respectively. Despite identical synthetic procedures, sulfate structure dramatically differs from selenate compound. Their common feature is an open-framework featuring two-dimensional system of channels occupied by protonated morpholino-N-acetic acid species. Coordination of Na atoms is different. In NaUSe, [(UO 2) 2 (SeO 4) 3(H 2O)] 2- layers are pillared by {Na 2O 8(H 2O) 2(Hmfa) 2} complexes to form a microporous framework. In NaUS, UO 7 and SO 4 polyhedra of [(UO 2)(SO 4) 2] 2- chains share common oxygen atoms with Na-centered tetrameric complexes providing a three-dimensional integrity of the structure. Both of the compounds are characterized by IR spectroscopy.

AB - The reaction of sodium N-morpholine acetate with selenic and sulfuric acid and uranyl nitrate results in the formation of two novel open-framework compounds, |Na(Hmfa)|[(UO 2) 2(SeO 4) 3(H 2O)](H 2O) 2 (NaUSe) and [Na 2(SO 3OH)(Hmfa)]|(UO 2)(SO 4) 2| (NaUS), respectively. Despite identical synthetic procedures, sulfate structure dramatically differs from selenate compound. Their common feature is an open-framework featuring two-dimensional system of channels occupied by protonated morpholino-N-acetic acid species. Coordination of Na atoms is different. In NaUSe, [(UO 2) 2 (SeO 4) 3(H 2O)] 2- layers are pillared by {Na 2O 8(H 2O) 2(Hmfa) 2} complexes to form a microporous framework. In NaUS, UO 7 and SO 4 polyhedra of [(UO 2)(SO 4) 2] 2- chains share common oxygen atoms with Na-centered tetrameric complexes providing a three-dimensional integrity of the structure. Both of the compounds are characterized by IR spectroscopy.

KW - open-framework materials

KW - selenates

KW - sulfates

KW - uranium

UR - http://www.scopus.com/inward/record.url?scp=85054410724&partnerID=8YFLogxK

U2 - 10.1515/zkri-2018-2103

DO - 10.1515/zkri-2018-2103

M3 - Article

VL - 234

SP - 109

EP - 118

JO - Zeitschfrift fur Kristallographie

JF - Zeitschfrift fur Kristallographie

SN - 0044-2968

IS - 2

ER -

ID: 34613200