Результаты исследований: Научные публикации в периодических изданиях › статья
One-Pot Synthesis and Asymmetric Oxidation of 2-Nitro-4-(Trifluoromethyl)Benzene Containing Sulfides. / Rodygin, Konstantin S.; Rubtsova, Svetlana A.; Kutchin, Alexander V.; Slepukhin, Pavel A.
в: Phosphorus, Sulfur and Silicon and the Related Elements, Том 186, № 9, 2011, стр. 1885-1894.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - One-Pot Synthesis and Asymmetric Oxidation of 2-Nitro-4-(Trifluoromethyl)Benzene Containing Sulfides
AU - Rodygin, Konstantin S.
AU - Rubtsova, Svetlana A.
AU - Kutchin, Alexander V.
AU - Slepukhin, Pavel A.
PY - 2011
Y1 - 2011
N2 - An efficient one-pot method for the prepn. of 2-nitro-4-(trifluoromethyl)phenyl sulfides from 1,1'-disulfanediylbis[2-nitro-4-(trifluoromethyl)benzene] is proposed. The corresponding enantiomerically enriched sulfoxides with up to 78% enantiomeric excess are prepd. by the asym. oxidn. of sulfides using a modified Sharpless method. The yield of sulfoxides decreases with an increase in the bulk of the aliph. group and with a decrease of the inductive effect of the hydrocarbon moiety on the sulfur atom.
AB - An efficient one-pot method for the prepn. of 2-nitro-4-(trifluoromethyl)phenyl sulfides from 1,1'-disulfanediylbis[2-nitro-4-(trifluoromethyl)benzene] is proposed. The corresponding enantiomerically enriched sulfoxides with up to 78% enantiomeric excess are prepd. by the asym. oxidn. of sulfides using a modified Sharpless method. The yield of sulfoxides decreases with an increase in the bulk of the aliph. group and with a decrease of the inductive effect of the hydrocarbon moiety on the sulfur atom.
U2 - 10.1080/10426507.2010.547893
DO - 10.1080/10426507.2010.547893
M3 - статья
VL - 186
SP - 1885
EP - 1894
JO - Phosphorus, Sulfur and Silicon and the Related Elements
JF - Phosphorus, Sulfur and Silicon and the Related Elements
SN - 1042-6507
IS - 9
ER -
ID: 5551397