DOI

  • Anastasiia V. Sokolova
  • Ivan D. Skurlov
  • Anton A. Babaev
  • Peter S. Perfenov
  • Maksim A. Miropoltsev
  • Denis V. Danilov
  • Mikhail A. Baranov
  • Ilya E. Kolesnikov
  • Aleksandra V. Koroleva
  • Evgeniy V. Zhizhin
  • Aleksandr P. Litvin
  • Anatoly V. Fedorov
  • Sergei A. Cherevkov
Doping the semiconductor nanocrystals is one of the most effective ways to obtain unique materials suitable for high-performance next-generation optoelectronic devices. In this study, we demonstrate a novel nanomaterial for the near-infrared spectral region. To do this, we developed a partial cation exchange reaction on the HgTe nanoplatelets, substituting Hg cations with Pb cations. Under the optimized reaction conditions and Pb precursor ratio, a photoluminescence band shifts to ~1100 nm with a quantum yield of 22%. Based on steady-state and transient optical spectroscopies, we suggest a model of photoexcitation relaxation in the HgTe:Pb nanoplatelets. We also demonstrate that the thin films of doped nanoplatelets possess superior electric properties compared to their pristine counterparts. These findings show that Pb-doped HgTe nanoplatelets are new perspective material for application in both light-emitting and light-detection devices operating in the near-infrared spectral region.
Язык оригиналарусский
Номер статьи4198
ЖурналNanomaterials
Том12
Номер выпуска23
DOI
СостояниеОпубликовано - 1 дек 2022

    Области исследований

  • cation exchange, nanoplatelets, near-infrared emission, photosensitivity

ID: 105695735