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Magnesium acetate – an effective electrophilic activator of the carbonyl group in transesterification of dialkylaziridine dicarboxylates. / Kazakova, Angelina V.; Androsov, Dmitriy V.; Konev, Alexander S.; Khlebnikov, Alexander F.

в: Chemistry of Heterocyclic Compounds, Том 56, № 7, 07.2020, стр. 875-880.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{e861d2641d7e43548f4a9188d1926e8d,
title = "Magnesium acetate – an effective electrophilic activator of the carbonyl group in transesterification of dialkylaziridine dicarboxylates",
abstract = "A method for transesterification of the ester groups in dialkylaziridine dicarboxylates by electrophilic activation of the carbonyl group in the presence of magnesium acetate with the preservation of the aziridine ring was developed and the use of modified aziridine dicarboxylates in the synthesis of sterically hindered derivatives of fullerenes C-60, 2',5'-disubstituted fulleropyrrolidines, was demonstrated.",
keywords = "1,3-dipolar cycloaddition, aziridines, electrophilic activation, fullerenes, stereodirected synthesis, transesterification, OXAZOLIDINES, AZOMETHINE YLIDES, AZIRIDINES, STRUCTURAL DIVERSITY, CYCLOADDITION, INHIBITION, STEREOSELECTIVE-SYNTHESIS",
author = "Kazakova, {Angelina V.} and Androsov, {Dmitriy V.} and Konev, {Alexander S.} and Khlebnikov, {Alexander F.}",
year = "2020",
month = jul,
doi = "10.1007/s10593-020-02744-y",
language = "English",
volume = "56",
pages = "875--880",
journal = "Chemistry of Heterocyclic Compounds",
issn = "0009-3122",
publisher = "Springer Nature",
number = "7",

}

RIS

TY - JOUR

T1 - Magnesium acetate – an effective electrophilic activator of the carbonyl group in transesterification of dialkylaziridine dicarboxylates

AU - Kazakova, Angelina V.

AU - Androsov, Dmitriy V.

AU - Konev, Alexander S.

AU - Khlebnikov, Alexander F.

PY - 2020/7

Y1 - 2020/7

N2 - A method for transesterification of the ester groups in dialkylaziridine dicarboxylates by electrophilic activation of the carbonyl group in the presence of magnesium acetate with the preservation of the aziridine ring was developed and the use of modified aziridine dicarboxylates in the synthesis of sterically hindered derivatives of fullerenes C-60, 2',5'-disubstituted fulleropyrrolidines, was demonstrated.

AB - A method for transesterification of the ester groups in dialkylaziridine dicarboxylates by electrophilic activation of the carbonyl group in the presence of magnesium acetate with the preservation of the aziridine ring was developed and the use of modified aziridine dicarboxylates in the synthesis of sterically hindered derivatives of fullerenes C-60, 2',5'-disubstituted fulleropyrrolidines, was demonstrated.

KW - 1,3-dipolar cycloaddition

KW - aziridines

KW - electrophilic activation

KW - fullerenes

KW - stereodirected synthesis

KW - transesterification

KW - OXAZOLIDINES

KW - AZOMETHINE YLIDES

KW - AZIRIDINES

KW - STRUCTURAL DIVERSITY

KW - CYCLOADDITION

KW - INHIBITION

KW - STEREOSELECTIVE-SYNTHESIS

UR - http://www.scopus.com/inward/record.url?scp=85089750928&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/c79ae7d3-e8f7-3b83-bc6b-f228d984400e/

U2 - 10.1007/s10593-020-02744-y

DO - 10.1007/s10593-020-02744-y

M3 - Article

AN - SCOPUS:85089750928

VL - 56

SP - 875

EP - 880

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

SN - 0009-3122

IS - 7

ER -

ID: 62157471