Research output: Contribution to journal › Article › peer-review
Magnesium acetate – an effective electrophilic activator of the carbonyl group in transesterification of dialkylaziridine dicarboxylates. / Kazakova, Angelina V.; Androsov, Dmitriy V.; Konev, Alexander S.; Khlebnikov, Alexander F.
In: Chemistry of Heterocyclic Compounds, Vol. 56, No. 7, 07.2020, p. 875-880.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Magnesium acetate – an effective electrophilic activator of the carbonyl group in transesterification of dialkylaziridine dicarboxylates
AU - Kazakova, Angelina V.
AU - Androsov, Dmitriy V.
AU - Konev, Alexander S.
AU - Khlebnikov, Alexander F.
PY - 2020/7
Y1 - 2020/7
N2 - A method for transesterification of the ester groups in dialkylaziridine dicarboxylates by electrophilic activation of the carbonyl group in the presence of magnesium acetate with the preservation of the aziridine ring was developed and the use of modified aziridine dicarboxylates in the synthesis of sterically hindered derivatives of fullerenes C-60, 2',5'-disubstituted fulleropyrrolidines, was demonstrated.
AB - A method for transesterification of the ester groups in dialkylaziridine dicarboxylates by electrophilic activation of the carbonyl group in the presence of magnesium acetate with the preservation of the aziridine ring was developed and the use of modified aziridine dicarboxylates in the synthesis of sterically hindered derivatives of fullerenes C-60, 2',5'-disubstituted fulleropyrrolidines, was demonstrated.
KW - 1,3-dipolar cycloaddition
KW - aziridines
KW - electrophilic activation
KW - fullerenes
KW - stereodirected synthesis
KW - transesterification
KW - OXAZOLIDINES
KW - AZOMETHINE YLIDES
KW - AZIRIDINES
KW - STRUCTURAL DIVERSITY
KW - CYCLOADDITION
KW - INHIBITION
KW - STEREOSELECTIVE-SYNTHESIS
UR - http://www.scopus.com/inward/record.url?scp=85089750928&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/c79ae7d3-e8f7-3b83-bc6b-f228d984400e/
U2 - 10.1007/s10593-020-02744-y
DO - 10.1007/s10593-020-02744-y
M3 - Article
AN - SCOPUS:85089750928
VL - 56
SP - 875
EP - 880
JO - Chemistry of Heterocyclic Compounds
JF - Chemistry of Heterocyclic Compounds
SN - 0009-3122
IS - 7
ER -
ID: 62157471