Результаты исследований: Научные публикации в периодических изданиях › статья
Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers. / Artem’ev, Alexander V.; Doronina, Evgeniya P.; Rakhmanova, Marianna I.; Sutyrina, Anastasiya O.; Bagryanskaya, Irina Yu.; Tolstoy, Peter M.; Gushchin, Artem L.; Mazur, Anton S.; Gusarovaa, Nina K.; Trofimov, Boris A.
в: New Journal of Chemistry, Том 40, 2016, стр. 10028-10040.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers
AU - Artem’ev, Alexander V.
AU - Doronina, Evgeniya P.
AU - Rakhmanova, Marianna I.
AU - Sutyrina, Anastasiya O.
AU - Bagryanskaya, Irina Yu.
AU - Tolstoy, Peter M.
AU - Gushchin, Artem L.
AU - Mazur, Anton S.
AU - Gusarovaa, Nina K.
AU - Trofimov, Boris A.
PY - 2016
Y1 - 2016
N2 - Tris(2-pyridyl)phosphine oxide reacts with CuSCN to form a variety of luminescent complexes, depending on the specified metal-to-ligand ratio and the solvent used, viz. mononuclear [Cu(N,N',N''-Py3P=O)(NCS)], dinuclear (N,N'-Py3P=O)Cu(SCN,NCS)Cu[(N,N'-Py3P=O)], their co-crystal (2 : 1, correspondingly) and trinuclear {Cu(NCS)[SCNCu(N,N',N''-Py3P=O)]2}. In the solid state, these complexes feature red-orange emission upon UV photoexcitation. The reaction of tris(2-pyridyl)phosphine with CuSCN quantitatively produces an almost insoluble coordination polymer, [Cu(Py3P)NCS]n, which exhibits bright green emission. The synthesized compounds are the first members of the hitherto unknown family of Cu(I) thiocyanate complexes supported by tripodal ligands.
AB - Tris(2-pyridyl)phosphine oxide reacts with CuSCN to form a variety of luminescent complexes, depending on the specified metal-to-ligand ratio and the solvent used, viz. mononuclear [Cu(N,N',N''-Py3P=O)(NCS)], dinuclear (N,N'-Py3P=O)Cu(SCN,NCS)Cu[(N,N'-Py3P=O)], their co-crystal (2 : 1, correspondingly) and trinuclear {Cu(NCS)[SCNCu(N,N',N''-Py3P=O)]2}. In the solid state, these complexes feature red-orange emission upon UV photoexcitation. The reaction of tris(2-pyridyl)phosphine with CuSCN quantitatively produces an almost insoluble coordination polymer, [Cu(Py3P)NCS]n, which exhibits bright green emission. The synthesized compounds are the first members of the hitherto unknown family of Cu(I) thiocyanate complexes supported by tripodal ligands.
KW - элементоорганические соединения
KW - твердотельная спектроскопия ЯМР
U2 - 10.1039/C6NJ02087A
DO - 10.1039/C6NJ02087A
M3 - Article
VL - 40
SP - 10028
EP - 10040
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
ER -
ID: 7644836