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Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers. / Artem’ev, Alexander V.; Doronina, Evgeniya P.; Rakhmanova, Marianna I.; Sutyrina, Anastasiya O.; Bagryanskaya, Irina Yu.; Tolstoy, Peter M.; Gushchin, Artem L.; Mazur, Anton S.; Gusarovaa, Nina K.; Trofimov, Boris A.

In: New Journal of Chemistry, Vol. 40, 2016, p. 10028-10040.

Research output: Contribution to journal › Article

Harvard

Artem’ev, AV, Doronina, EP, Rakhmanova, MI, Sutyrina, AO, Bagryanskaya, IY, Tolstoy, PM, Gushchin, AL, Mazur, AS, Gusarovaa, NK & Trofimov, BA 2016, 'Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers', New Journal of Chemistry, vol. 40, pp. 10028-10040. https://doi.org/10.1039/C6NJ02087A

APA

Artem’ev, A. V., Doronina, E. P., Rakhmanova, M. I., Sutyrina, A. O., Bagryanskaya, I. Y., Tolstoy, P. M., Gushchin, A. L., Mazur, A. S., Gusarovaa, N. K., & Trofimov, B. A. (2016). Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers. New Journal of Chemistry, 40, 10028-10040. https://doi.org/10.1039/C6NJ02087A

Vancouver

Artem’ev AV, Doronina EP, Rakhmanova MI, Sutyrina AO, Bagryanskaya IY, Tolstoy PM et al. Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers. New Journal of Chemistry. 2016;40:10028-10040. https://doi.org/10.1039/C6NJ02087A

Author

Artem’ev, Alexander V. ; Doronina, Evgeniya P. ; Rakhmanova, Marianna I. ; Sutyrina, Anastasiya O. ; Bagryanskaya, Irina Yu. ; Tolstoy, Peter M. ; Gushchin, Artem L. ; Mazur, Anton S. ; Gusarovaa, Nina K. ; Trofimov, Boris A. / Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers. In: New Journal of Chemistry. 2016 ; Vol. 40. pp. 10028-10040.

BibTeX

@article{adba74a262aa4b5b8e89014ed3d6f523,
title = "Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers",
abstract = "Tris(2-pyridyl)phosphine oxide reacts with CuSCN to form a variety of luminescent complexes, depending on the specified metal-to-ligand ratio and the solvent used, viz. mononuclear [Cu(N,N',N''-Py3P=O)(NCS)], dinuclear (N,N'-Py3P=O)Cu(SCN,NCS)Cu[(N,N'-Py3P=O)], their co-crystal (2 : 1, correspondingly) and trinuclear {Cu(NCS)[SCNCu(N,N',N''-Py3P=O)]2}. In the solid state, these complexes feature red-orange emission upon UV photoexcitation. The reaction of tris(2-pyridyl)phosphine with CuSCN quantitatively produces an almost insoluble coordination polymer, [Cu(Py3P)NCS]n, which exhibits bright green emission. The synthesized compounds are the first members of the hitherto unknown family of Cu(I) thiocyanate complexes supported by tripodal ligands.",
keywords = "элементоорганические соединения, твердотельная спектроскопия ЯМР",
author = "Artem{\textquoteright}ev, {Alexander V.} and Doronina, {Evgeniya P.} and Rakhmanova, {Marianna I.} and Sutyrina, {Anastasiya O.} and Bagryanskaya, {Irina Yu.} and Tolstoy, {Peter M.} and Gushchin, {Artem L.} and Mazur, {Anton S.} and Gusarovaa, {Nina K.} and Trofimov, {Boris A.}",
year = "2016",
doi = "10.1039/C6NJ02087A",
language = "English",
volume = "40",
pages = "10028--10040",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "Royal Society of Chemistry",

}

RIS

TY - JOUR

T1 - Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers

AU - Artem’ev, Alexander V.

AU - Doronina, Evgeniya P.

AU - Rakhmanova, Marianna I.

AU - Sutyrina, Anastasiya O.

AU - Bagryanskaya, Irina Yu.

AU - Tolstoy, Peter M.

AU - Gushchin, Artem L.

AU - Mazur, Anton S.

AU - Gusarovaa, Nina K.

AU - Trofimov, Boris A.

PY - 2016

Y1 - 2016

N2 - Tris(2-pyridyl)phosphine oxide reacts with CuSCN to form a variety of luminescent complexes, depending on the specified metal-to-ligand ratio and the solvent used, viz. mononuclear [Cu(N,N',N''-Py3P=O)(NCS)], dinuclear (N,N'-Py3P=O)Cu(SCN,NCS)Cu[(N,N'-Py3P=O)], their co-crystal (2 : 1, correspondingly) and trinuclear {Cu(NCS)[SCNCu(N,N',N''-Py3P=O)]2}. In the solid state, these complexes feature red-orange emission upon UV photoexcitation. The reaction of tris(2-pyridyl)phosphine with CuSCN quantitatively produces an almost insoluble coordination polymer, [Cu(Py3P)NCS]n, which exhibits bright green emission. The synthesized compounds are the first members of the hitherto unknown family of Cu(I) thiocyanate complexes supported by tripodal ligands.

AB - Tris(2-pyridyl)phosphine oxide reacts with CuSCN to form a variety of luminescent complexes, depending on the specified metal-to-ligand ratio and the solvent used, viz. mononuclear [Cu(N,N',N''-Py3P=O)(NCS)], dinuclear (N,N'-Py3P=O)Cu(SCN,NCS)Cu[(N,N'-Py3P=O)], their co-crystal (2 : 1, correspondingly) and trinuclear {Cu(NCS)[SCNCu(N,N',N''-Py3P=O)]2}. In the solid state, these complexes feature red-orange emission upon UV photoexcitation. The reaction of tris(2-pyridyl)phosphine with CuSCN quantitatively produces an almost insoluble coordination polymer, [Cu(Py3P)NCS]n, which exhibits bright green emission. The synthesized compounds are the first members of the hitherto unknown family of Cu(I) thiocyanate complexes supported by tripodal ligands.

KW - элементоорганические соединения

KW - твердотельная спектроскопия ЯМР

U2 - 10.1039/C6NJ02087A

DO - 10.1039/C6NJ02087A

M3 - Article

VL - 40

SP - 10028

EP - 10040

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

ER -

ID: 7644836