Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Line shapes of 1s → π* excited molecular clusters. / Pavlychev, A. A.; Flesch, R.; Rühl, E.
в: Physical Review A - Atomic, Molecular, and Optical Physics, Том 70, № 1, 015201, 01.01.2004.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Line shapes of 1s → π* excited molecular clusters
AU - Pavlychev, A. A.
AU - Flesch, R.
AU - Rühl, E.
PY - 2004/1/1
Y1 - 2004/1/1
N2 - The effect of intermolecular interactions on the vibrational fine structure of 1s → π excitations in free and clustered carbon monoxide and nitrogen was examined. Small, but distinct spectral changes were observed, including line broadening, changes in intensity and spectral shifts. Using a simple model, these changes were assigned in terms of variations in motion of the core-excited molecule within the molecular clusters. Contributions from intra- and inter-molecular vibrations in core-excited clusters that contribute to the experimentally observed spectral changes, were described.
AB - The effect of intermolecular interactions on the vibrational fine structure of 1s → π excitations in free and clustered carbon monoxide and nitrogen was examined. Small, but distinct spectral changes were observed, including line broadening, changes in intensity and spectral shifts. Using a simple model, these changes were assigned in terms of variations in motion of the core-excited molecule within the molecular clusters. Contributions from intra- and inter-molecular vibrations in core-excited clusters that contribute to the experimentally observed spectral changes, were described.
UR - http://www.scopus.com/inward/record.url?scp=19244366718&partnerID=8YFLogxK
U2 - 10.1103/PhysRevA.70.015201
DO - 10.1103/PhysRevA.70.015201
M3 - Article
VL - 70
JO - Physical Review A - Atomic, Molecular, and Optical Physics
JF - Physical Review A - Atomic, Molecular, and Optical Physics
SN - 1050-2947
IS - 1
M1 - 015201
ER -
ID: 5345761