Line shapes of 1s → π* excited molecular clusters

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Line shapes of 1s → π* excited molecular clusters. / Pavlychev, A. A.; Flesch, R.; Rühl, E.

In: Physical Review A - Atomic, Molecular, and Optical Physics, Vol. 70, No. 1, 015201, 01.01.2004.

Research output: Contribution to journal › Article › peer-review

Author

Pavlychev, A. A. ; Flesch, R. ; Rühl, E. / Line shapes of 1s → π* excited molecular clusters. In: Physical Review A - Atomic, Molecular, and Optical Physics. 2004 ; Vol. 70, No. 1.

BibTeX

@article{8b36570f9bdb436eb288ac45f0c12102,

title = "Line shapes of 1s → π* excited molecular clusters",

abstract = "The effect of intermolecular interactions on the vibrational fine structure of 1s → π excitations in free and clustered carbon monoxide and nitrogen was examined. Small, but distinct spectral changes were observed, including line broadening, changes in intensity and spectral shifts. Using a simple model, these changes were assigned in terms of variations in motion of the core-excited molecule within the molecular clusters. Contributions from intra- and inter-molecular vibrations in core-excited clusters that contribute to the experimentally observed spectral changes, were described.",

author = "Pavlychev, {A. A.} and R. Flesch and E. R{\"u}hl",

year = "2004",

month = jan,

day = "1",

doi = "10.1103/PhysRevA.70.015201",

language = "English",

volume = "70",

journal = "Physical Review A - Atomic, Molecular, and Optical Physics",

issn = "1050-2947",

publisher = "American Physical Society",

number = "1",

}

RIS

TY - JOUR

T1 - Line shapes of 1s → π* excited molecular clusters

AU - Pavlychev, A. A.

AU - Flesch, R.

AU - Rühl, E.

PY - 2004/1/1

Y1 - 2004/1/1

N2 - The effect of intermolecular interactions on the vibrational fine structure of 1s → π excitations in free and clustered carbon monoxide and nitrogen was examined. Small, but distinct spectral changes were observed, including line broadening, changes in intensity and spectral shifts. Using a simple model, these changes were assigned in terms of variations in motion of the core-excited molecule within the molecular clusters. Contributions from intra- and inter-molecular vibrations in core-excited clusters that contribute to the experimentally observed spectral changes, were described.

AB - The effect of intermolecular interactions on the vibrational fine structure of 1s → π excitations in free and clustered carbon monoxide and nitrogen was examined. Small, but distinct spectral changes were observed, including line broadening, changes in intensity and spectral shifts. Using a simple model, these changes were assigned in terms of variations in motion of the core-excited molecule within the molecular clusters. Contributions from intra- and inter-molecular vibrations in core-excited clusters that contribute to the experimentally observed spectral changes, were described.

UR - http://www.scopus.com/inward/record.url?scp=19244366718&partnerID=8YFLogxK

U2 - 10.1103/PhysRevA.70.015201

DO - 10.1103/PhysRevA.70.015201

M3 - Article

VL - 70

JO - Physical Review A - Atomic, Molecular, and Optical Physics

JF - Physical Review A - Atomic, Molecular, and Optical Physics

SN - 1050-2947

IS - 1

M1 - 015201

ER -

ID: 5345761