TY - JOUR

T1 - IR-IR double-resonance studies of vibrational relaxation of CD3F in solid and liquid Xe, Kr, Ar solutions near the melting point

AU - Rutkowski, K. S.

PY - 1998/10/15

Y1 - 1998/10/15

N2 - Vibrational energy relaxation has been studied for CD3F diluted in liquid and solid Xe, Kr, Ar near the melting points. On solidification of the Xe and Kr, a hopping increase of the relaxation time is revealed, whereas the liquid to solid-state transition in Ar solution is accompanied by a small decrease in time. The temperature dependence of the vibrational relaxation rate, obtained on the basis of low-density gas-phase, liquid, solid and low-temperature matrix measurements, is discussed in terms of simple binary and collective approaches.

AB - Vibrational energy relaxation has been studied for CD3F diluted in liquid and solid Xe, Kr, Ar near the melting points. On solidification of the Xe and Kr, a hopping increase of the relaxation time is revealed, whereas the liquid to solid-state transition in Ar solution is accompanied by a small decrease in time. The temperature dependence of the vibrational relaxation rate, obtained on the basis of low-density gas-phase, liquid, solid and low-temperature matrix measurements, is discussed in terms of simple binary and collective approaches.

UR - http://www.scopus.com/inward/record.url?scp=0032361030&partnerID=8YFLogxK

U2 - 10.1016/S0301-0104(98)00242-0

DO - 10.1016/S0301-0104(98)00242-0

M3 - Article

AN - SCOPUS:0032361030

VL - 237

SP - 403

EP - 411

JO - Chemical Physics

JF - Chemical Physics

SN - 0301-0104

IS - 3

ER -