Research output: Contribution to journal › Article › peer-review
IR-IR double-resonance studies of vibrational relaxation of CD3F in solid and liquid Xe, Kr, Ar solutions near the melting point. / Rutkowski, K. S.
In: Chemical Physics, Vol. 237, No. 3, 15.10.1998, p. 403-411.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - IR-IR double-resonance studies of vibrational relaxation of CD3F in solid and liquid Xe, Kr, Ar solutions near the melting point
AU - Rutkowski, K. S.
PY - 1998/10/15
Y1 - 1998/10/15
N2 - Vibrational energy relaxation has been studied for CD3F diluted in liquid and solid Xe, Kr, Ar near the melting points. On solidification of the Xe and Kr, a hopping increase of the relaxation time is revealed, whereas the liquid to solid-state transition in Ar solution is accompanied by a small decrease in time. The temperature dependence of the vibrational relaxation rate, obtained on the basis of low-density gas-phase, liquid, solid and low-temperature matrix measurements, is discussed in terms of simple binary and collective approaches.
AB - Vibrational energy relaxation has been studied for CD3F diluted in liquid and solid Xe, Kr, Ar near the melting points. On solidification of the Xe and Kr, a hopping increase of the relaxation time is revealed, whereas the liquid to solid-state transition in Ar solution is accompanied by a small decrease in time. The temperature dependence of the vibrational relaxation rate, obtained on the basis of low-density gas-phase, liquid, solid and low-temperature matrix measurements, is discussed in terms of simple binary and collective approaches.
UR - http://www.scopus.com/inward/record.url?scp=0032361030&partnerID=8YFLogxK
U2 - 10.1016/S0301-0104(98)00242-0
DO - 10.1016/S0301-0104(98)00242-0
M3 - Article
AN - SCOPUS:0032361030
VL - 237
SP - 403
EP - 411
JO - Chemical Physics
JF - Chemical Physics
SN - 0301-0104
IS - 3
ER -
ID: 36464266