Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Iodonium and Telluronium Triflates Serving as Noncovalent Organocatalysts Provide Catalytic Effect in the Schiff Condensation Due to Different Reasons. / Болотин, Дмитрий Сергеевич; Путнин, Иван Олегович; Сысоева, Александра Александровна; Ильин, Михаил Вячеславович.
в: ChemCatChem, 15.06.2024.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Iodonium and Telluronium Triflates Serving as Noncovalent Organocatalysts Provide Catalytic Effect in the Schiff Condensation Due to Different Reasons
AU - Болотин, Дмитрий Сергеевич
AU - Путнин, Иван Олегович
AU - Сысоева, Александра Александровна
AU - Ильин, Михаил Вячеславович
PY - 2024/6/15
Y1 - 2024/6/15
N2 - Sulfonium, selenonium, telluronium triflates, as well as chloronium, bromonium, and iodonium triflates have been examined in the model Schiff condensation as chalcogen‐ and halogen bond donating organocatalysts, respectively. The kinetic data indicated that the catalytic effect of the telluronium salt is provided via the decrease of enthalpy of activation of the reaction, whereas the catalytic effect of the iodonium salt — unexpectedly — is caused by the decrease of the value of the entropy of activation. In addition, it was experimentally shown that the catalytic activity of sulfonium and selenonium is significantly lower than that of chloronium and bromonium salts, but the latter pair of species is significantly less stable under the reaction conditions than the former pair.
AB - Sulfonium, selenonium, telluronium triflates, as well as chloronium, bromonium, and iodonium triflates have been examined in the model Schiff condensation as chalcogen‐ and halogen bond donating organocatalysts, respectively. The kinetic data indicated that the catalytic effect of the telluronium salt is provided via the decrease of enthalpy of activation of the reaction, whereas the catalytic effect of the iodonium salt — unexpectedly — is caused by the decrease of the value of the entropy of activation. In addition, it was experimentally shown that the catalytic activity of sulfonium and selenonium is significantly lower than that of chloronium and bromonium salts, but the latter pair of species is significantly less stable under the reaction conditions than the former pair.
UR - https://www.mendeley.com/catalogue/7b83ff77-7e12-32a8-9f98-c8a4f167befa/
U2 - 10.1002/cctc.202400672
DO - 10.1002/cctc.202400672
M3 - Article
JO - ChemCatChem
JF - ChemCatChem
SN - 1867-3880
ER -
ID: 120911477