DOI

The effect of hydrostatic pressure on the ionic conductivities in α-PbF2, β-PbF2, β-Pb1-x MxmF2+(m-2)x (where Mm=Na+, Cd2+, Tb3+, U4+), PbSnF4, RbSn2F5, LaF3 and LaF3-1.2 mol.% CaF2 has been investigated in the temperature range between 300 K and 700 K for pressures up to 0.30 GPa (for β-PbF2, PbSnF4, RbSn2F5) and 0.8 GPa (for LaF3). The activation volumes of defect formation and migration, impurity defect segregation and dissociation were determined from the effect of pressure on conductivity. Keyesí treatment based on the strain energy Zener model in Grüneisen approximation was used to estimate theoretical values of the activation volumes.

Язык оригиналаанглийский
Страницы (с-по)274-278
Число страниц5
ЖурналIonics
Том1
Номер выпуска3
DOI
СостояниеОпубликовано - 1 мая 1995

    Предметные области Scopus

  • Химическая технология (все)
  • Материаловедение (все)
  • Технология (все)
  • Физика и астрономия (все)

ID: 52787508