DOI

The effect of hydrostatic pressure on the ionic conductivities in α-PbF2, β-PbF2, β-Pb1-x MxmF2+(m-2)x (where Mm=Na+, Cd2+, Tb3+, U4+), PbSnF4, RbSn2F5, LaF3 and LaF3-1.2 mol.% CaF2 has been investigated in the temperature range between 300 K and 700 K for pressures up to 0.30 GPa (for β-PbF2, PbSnF4, RbSn2F5) and 0.8 GPa (for LaF3). The activation volumes of defect formation and migration, impurity defect segregation and dissociation were determined from the effect of pressure on conductivity. Keyesí treatment based on the strain energy Zener model in Grüneisen approximation was used to estimate theoretical values of the activation volumes.

Original languageEnglish
Pages (from-to)274-278
Number of pages5
JournalIonics
Volume1
Issue number3
DOIs
StatePublished - 1 May 1995

    Scopus subject areas

  • Chemical Engineering(all)
  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

ID: 52787508