Результаты исследований: Научные публикации в периодических изданиях › статья
Grand potential in thermodynamics of solid bodies and surfaces. / Rusanov, A.I.; Shchekin, A.K.; Tatyanenko, D.V.
в: Journal of Chemical Physics, Том 131, № 16, 2009, стр. 161104_1-4.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Grand potential in thermodynamics of solid bodies and surfaces
AU - Rusanov, A.I.
AU - Shchekin, A.K.
AU - Tatyanenko, D.V.
PY - 2009
Y1 - 2009
N2 - Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested. This allows generalizing the definition of Gibbs’ quantity σ (surface work often called the solid-fluid interfacial free energ) at a planar surface as an excess grand thermodynamic potential per unit surface area that (1) does not depend on the dividing surface location and (2) is common for fluids and solids.
AB - Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested. This allows generalizing the definition of Gibbs’ quantity σ (surface work often called the solid-fluid interfacial free energ) at a planar surface as an excess grand thermodynamic potential per unit surface area that (1) does not depend on the dividing surface location and (2) is common for fluids and solids.
KW - chemical potential
KW - free energy
U2 - 10.1063/1.3254324
DO - 10.1063/1.3254324
M3 - Article
VL - 131
SP - 161104_1-4
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 16
ER -
ID: 5090807