Standard

Grand potential in thermodynamics of solid bodies and surfaces. / Rusanov, A.I.; Shchekin, A.K.; Tatyanenko, D.V.

In: Journal of Chemical Physics, Vol. 131, No. 16, 2009, p. 161104_1-4.

Research output: Contribution to journalArticle

Harvard

APA

Vancouver

Author

Rusanov, A.I. ; Shchekin, A.K. ; Tatyanenko, D.V. / Grand potential in thermodynamics of solid bodies and surfaces. In: Journal of Chemical Physics. 2009 ; Vol. 131, No. 16. pp. 161104_1-4.

BibTeX

@article{e3ed08e4a2ea44e6a1d9e1552210deff,
title = "Grand potential in thermodynamics of solid bodies and surfaces",
abstract = "Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested. This allows generalizing the definition of Gibbs{\textquoteright} quantity σ (surface work often called the solid-fluid interfacial free energ) at a planar surface as an excess grand thermodynamic potential per unit surface area that (1) does not depend on the dividing surface location and (2) is common for fluids and solids.",
keywords = "chemical potential, free energy",
author = "A.I. Rusanov and A.K. Shchekin and D.V. Tatyanenko",
year = "2009",
doi = "10.1063/1.3254324",
language = "English",
volume = "131",
pages = "161104_1--4",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "16",

}

RIS

TY - JOUR

T1 - Grand potential in thermodynamics of solid bodies and surfaces

AU - Rusanov, A.I.

AU - Shchekin, A.K.

AU - Tatyanenko, D.V.

PY - 2009

Y1 - 2009

N2 - Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested. This allows generalizing the definition of Gibbs’ quantity σ (surface work often called the solid-fluid interfacial free energ) at a planar surface as an excess grand thermodynamic potential per unit surface area that (1) does not depend on the dividing surface location and (2) is common for fluids and solids.

AB - Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested. This allows generalizing the definition of Gibbs’ quantity σ (surface work often called the solid-fluid interfacial free energ) at a planar surface as an excess grand thermodynamic potential per unit surface area that (1) does not depend on the dividing surface location and (2) is common for fluids and solids.

KW - chemical potential

KW - free energy

U2 - 10.1063/1.3254324

DO - 10.1063/1.3254324

M3 - Article

VL - 131

SP - 161104_1-4

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 16

ER -

ID: 5090807