Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Formation of the structure of interpolyelectrolyte complex in solid state: Role of comb-like amphiphilic polyelectrolyte. / Fetin, P.A.; Zorin, I.M.; Mechtaeva, E.V.; Voeiko, D.A.; Zorina, N.A.; Gavrilova, D.A.; Bilibin, A.Yu.
в: European Polymer Journal, Том 116, 01.07.2019, стр. 562-569.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Formation of the structure of interpolyelectrolyte complex in solid state: Role of comb-like amphiphilic polyelectrolyte
AU - Fetin, P.A.
AU - Zorin, I.M.
AU - Mechtaeva, E.V.
AU - Voeiko, D.A.
AU - Zorina, N.A.
AU - Gavrilova, D.A.
AU - Bilibin, A.Yu.
PY - 2019/7/1
Y1 - 2019/7/1
N2 - Interpolyelectrolyte complexes (IPECs) were obtained from linear polyanion poly (2-acrylamido-2-methylpropanesulfonic acid) (pAMPS) and comb-like polycation poly(11-acryloyloxyundecyltrimethylammonium) bromide (pAUTA-Br) using different strategies comprising of mixing polyelectrolyte solutions in homogeneous and heterogeneous conditions and the polymerization of ionic monomer in the presence of opposite-charged polyelectrolyte. The supramolecular structure of IPEC in a solid state was studied by SAXD. The hexagonal or cubic order was revealed by IPEC obtained in different conditions. The lattice unit cell size appeared to be dependent on the solvent thermodynamic quality of the used polymers. These structures are pre-formed in solutions of comb-like self-organized components and fixed in a solid state in the course of kinetically driven IPEC formation.
AB - Interpolyelectrolyte complexes (IPECs) were obtained from linear polyanion poly (2-acrylamido-2-methylpropanesulfonic acid) (pAMPS) and comb-like polycation poly(11-acryloyloxyundecyltrimethylammonium) bromide (pAUTA-Br) using different strategies comprising of mixing polyelectrolyte solutions in homogeneous and heterogeneous conditions and the polymerization of ionic monomer in the presence of opposite-charged polyelectrolyte. The supramolecular structure of IPEC in a solid state was studied by SAXD. The hexagonal or cubic order was revealed by IPEC obtained in different conditions. The lattice unit cell size appeared to be dependent on the solvent thermodynamic quality of the used polymers. These structures are pre-formed in solutions of comb-like self-organized components and fixed in a solid state in the course of kinetically driven IPEC formation.
KW - Comb-like polyelectrolyte
KW - Interpolyelectrolyte complex
KW - Self-assembly
KW - Small-angle X-rays diffraction
KW - Supramolecular structure
KW - Surfactant polymerization
KW - MEMBRANES
KW - SEPARATION
KW - PERVAPORATION
UR - http://www.scopus.com/inward/record.url?scp=85064901885&partnerID=8YFLogxK
UR - http://www.mendeley.com/research/formation-structure-interpolyelectrolyte-complex-solid-state-role-comblike-amphiphilic-polyelectroly
U2 - 10.1016/j.eurpolymj.2019.04.052
DO - 10.1016/j.eurpolymj.2019.04.052
M3 - Article
VL - 116
SP - 562
EP - 569
JO - European Polymer Journal
JF - European Polymer Journal
SN - 0014-3057
ER -
ID: 41435006