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@article{a4ecbd8807a442c2a0de2f9069286edb,
title = "Formation of the structure of interpolyelectrolyte complex in solid state: Role of comb-like amphiphilic polyelectrolyte",
abstract = "Interpolyelectrolyte complexes (IPECs) were obtained from linear polyanion poly (2-acrylamido-2-methylpropanesulfonic acid) (pAMPS) and comb-like polycation poly(11-acryloyloxyundecyltrimethylammonium) bromide (pAUTA-Br) using different strategies comprising of mixing polyelectrolyte solutions in homogeneous and heterogeneous conditions and the polymerization of ionic monomer in the presence of opposite-charged polyelectrolyte. The supramolecular structure of IPEC in a solid state was studied by SAXD. The hexagonal or cubic order was revealed by IPEC obtained in different conditions. The lattice unit cell size appeared to be dependent on the solvent thermodynamic quality of the used polymers. These structures are pre-formed in solutions of comb-like self-organized components and fixed in a solid state in the course of kinetically driven IPEC formation.",
keywords = "Comb-like polyelectrolyte, Interpolyelectrolyte complex, Self-assembly, Small-angle X-rays diffraction, Supramolecular structure, Surfactant polymerization, MEMBRANES, SEPARATION, PERVAPORATION",
author = "P.A. Fetin and I.M. Zorin and E.V. Mechtaeva and D.A. Voeiko and N.A. Zorina and D.A. Gavrilova and A.Yu. Bilibin",
year = "2019",
month = jul,
day = "1",
doi = "10.1016/j.eurpolymj.2019.04.052",
language = "English",
volume = "116",
pages = "562--569",
journal = "European Polymer Journal",
issn = "0014-3057",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Formation of the structure of interpolyelectrolyte complex in solid state: Role of comb-like amphiphilic polyelectrolyte

AU - Fetin, P.A.

AU - Zorin, I.M.

AU - Mechtaeva, E.V.

AU - Voeiko, D.A.

AU - Zorina, N.A.

AU - Gavrilova, D.A.

AU - Bilibin, A.Yu.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Interpolyelectrolyte complexes (IPECs) were obtained from linear polyanion poly (2-acrylamido-2-methylpropanesulfonic acid) (pAMPS) and comb-like polycation poly(11-acryloyloxyundecyltrimethylammonium) bromide (pAUTA-Br) using different strategies comprising of mixing polyelectrolyte solutions in homogeneous and heterogeneous conditions and the polymerization of ionic monomer in the presence of opposite-charged polyelectrolyte. The supramolecular structure of IPEC in a solid state was studied by SAXD. The hexagonal or cubic order was revealed by IPEC obtained in different conditions. The lattice unit cell size appeared to be dependent on the solvent thermodynamic quality of the used polymers. These structures are pre-formed in solutions of comb-like self-organized components and fixed in a solid state in the course of kinetically driven IPEC formation.

AB - Interpolyelectrolyte complexes (IPECs) were obtained from linear polyanion poly (2-acrylamido-2-methylpropanesulfonic acid) (pAMPS) and comb-like polycation poly(11-acryloyloxyundecyltrimethylammonium) bromide (pAUTA-Br) using different strategies comprising of mixing polyelectrolyte solutions in homogeneous and heterogeneous conditions and the polymerization of ionic monomer in the presence of opposite-charged polyelectrolyte. The supramolecular structure of IPEC in a solid state was studied by SAXD. The hexagonal or cubic order was revealed by IPEC obtained in different conditions. The lattice unit cell size appeared to be dependent on the solvent thermodynamic quality of the used polymers. These structures are pre-formed in solutions of comb-like self-organized components and fixed in a solid state in the course of kinetically driven IPEC formation.

KW - Comb-like polyelectrolyte

KW - Interpolyelectrolyte complex

KW - Self-assembly

KW - Small-angle X-rays diffraction

KW - Supramolecular structure

KW - Surfactant polymerization

KW - MEMBRANES

KW - SEPARATION

KW - PERVAPORATION

UR - http://www.scopus.com/inward/record.url?scp=85064901885&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/formation-structure-interpolyelectrolyte-complex-solid-state-role-comblike-amphiphilic-polyelectroly

U2 - 10.1016/j.eurpolymj.2019.04.052

DO - 10.1016/j.eurpolymj.2019.04.052

M3 - Article

VL - 116

SP - 562

EP - 569

JO - European Polymer Journal

JF - European Polymer Journal

SN - 0014-3057

ER -

ID: 41435006