Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Electric field assisted alignment of monoatomic carbon chains. / Kutrovskaya, Stella; Chestnov, Igor; Osipov, Anton; Samyshkin, Vlad; Sapegina, Irina; Kavokin, Alexey; Kucherik, Alexey.
в: Scientific Reports, Том 10, № 1, 9709, 16.06.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Electric field assisted alignment of monoatomic carbon chains
AU - Kutrovskaya, Stella
AU - Chestnov, Igor
AU - Osipov, Anton
AU - Samyshkin, Vlad
AU - Sapegina, Irina
AU - Kavokin, Alexey
AU - Kucherik, Alexey
PY - 2020/6/16
Y1 - 2020/6/16
N2 - We stabilize monoatomic carbon chains in water by attaching them to gold nanoparticles (NPs) by means of the laser ablation process. Resulting nanoobjects represent pairs of NPs connected by multiple straight carbon chains of several nanometer lengths. If NPs at the opposite ends of a chain differ in size, the structure acquires a dipole moment due to the difference in work functions of the two NPs. We take advantage of the dipole polarisation of carbon chains for ordering them by the external electric field. We deposit them on a glass substrate by the sputtering method in the presence of static electric fields of magnitudes up to 105 V/m. The formation of one-dimensional carbyne quasi-crystals deposited on a substrate is evidenced by high-resolution TEM and X-ray diffraction measurements. The original kinetic model describing the dynamics of ballistically flowing nano-dipoles reproduces the experimental diagram of orientation of the deposited chains.
AB - We stabilize monoatomic carbon chains in water by attaching them to gold nanoparticles (NPs) by means of the laser ablation process. Resulting nanoobjects represent pairs of NPs connected by multiple straight carbon chains of several nanometer lengths. If NPs at the opposite ends of a chain differ in size, the structure acquires a dipole moment due to the difference in work functions of the two NPs. We take advantage of the dipole polarisation of carbon chains for ordering them by the external electric field. We deposit them on a glass substrate by the sputtering method in the presence of static electric fields of magnitudes up to 105 V/m. The formation of one-dimensional carbyne quasi-crystals deposited on a substrate is evidenced by high-resolution TEM and X-ray diffraction measurements. The original kinetic model describing the dynamics of ballistically flowing nano-dipoles reproduces the experimental diagram of orientation of the deposited chains.
KW - FERMI-LEVEL EQUILIBRATION
KW - LASER-INDUCED SYNTHESIS
KW - WORK FUNCTION
KW - CARBYNE
KW - POTENTIALS
KW - TRANSPORT
UR - http://www.scopus.com/inward/record.url?scp=85086668258&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/64a11fcc-6c1c-314b-a99d-14ac8d9c2f8e/
U2 - 10.1038/s41598-020-65356-8
DO - 10.1038/s41598-020-65356-8
M3 - Article
C2 - 32546798
AN - SCOPUS:85086668258
VL - 10
JO - Scientific Reports
JF - Scientific Reports
SN - 2045-2322
IS - 1
M1 - 9709
ER -
ID: 62025546