Development of the R.L. Muller model of the microheterogeneous structure of glass and its application for various glass types

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Development of the R.L. Muller model of the microheterogeneous structure of glass and its application for various glass types. / Pronkin, A. A.; Murin, I. V.; Sokolov, I. A.

в: Glass Physics and Chemistry, Том 41, № 1, 2015, стр. 35-41.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{b21ccfb837b544898083d66c62d8e88d,

title = "Development of the R.L. Muller model of the microheterogeneous structure of glass and its application for various glass types",

abstract = "The possibility of the application of the R.L. Muller model of the microheterogeneous structure of glass for the description of the nature of the conduction various glass classes, the electric conduction of which is due to the migration of cations, anions and the combined migration of cations and electrons, has been considered. It was shown that the appearance and the subsequent increase in the ionic conduction can be explained using the concentration variation of the blocking extent function (γ), which is calculated based on the analysis of the ratio of the concentration of nonpolar and polar structural fragments—structural-chemical units in the bulk of glass. On the whole, the methodology of the calculation of the concentration γ values for various glass systems coincides, except for some features in halogen-containing systems that required additional specifications.",

keywords = "activation energy of electric conduction, electric conduction, microheterogeneous structure of glass, polar (ionogenic and blocking) and nonpolar (blocking) structural-chemical units, true transport numbers",

author = "Pronkin, {A. A.} and Murin, {I. V.} and Sokolov, {I. A.}",

note = "Publisher Copyright: {\textcopyright} 2015, Pleiades Publishing, Ltd.",

year = "2015",

doi = "10.1134/S1087659615010228",

language = "English",

volume = "41",

pages = "35--41",

journal = "Glass Physics and Chemistry",

issn = "1087-6596",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "1",

}

RIS

TY - JOUR

T1 - Development of the R.L. Muller model of the microheterogeneous structure of glass and its application for various glass types

AU - Pronkin, A. A.

AU - Murin, I. V.

AU - Sokolov, I. A.

PY - 2015

Y1 - 2015

N2 - The possibility of the application of the R.L. Muller model of the microheterogeneous structure of glass for the description of the nature of the conduction various glass classes, the electric conduction of which is due to the migration of cations, anions and the combined migration of cations and electrons, has been considered. It was shown that the appearance and the subsequent increase in the ionic conduction can be explained using the concentration variation of the blocking extent function (γ), which is calculated based on the analysis of the ratio of the concentration of nonpolar and polar structural fragments—structural-chemical units in the bulk of glass. On the whole, the methodology of the calculation of the concentration γ values for various glass systems coincides, except for some features in halogen-containing systems that required additional specifications.

AB - The possibility of the application of the R.L. Muller model of the microheterogeneous structure of glass for the description of the nature of the conduction various glass classes, the electric conduction of which is due to the migration of cations, anions and the combined migration of cations and electrons, has been considered. It was shown that the appearance and the subsequent increase in the ionic conduction can be explained using the concentration variation of the blocking extent function (γ), which is calculated based on the analysis of the ratio of the concentration of nonpolar and polar structural fragments—structural-chemical units in the bulk of glass. On the whole, the methodology of the calculation of the concentration γ values for various glass systems coincides, except for some features in halogen-containing systems that required additional specifications.

KW - activation energy of electric conduction

KW - electric conduction

KW - microheterogeneous structure of glass

KW - polar (ionogenic and blocking) and nonpolar (blocking) structural-chemical units

KW - true transport numbers

UR - http://www.scopus.com/inward/record.url?scp=84922816780&partnerID=8YFLogxK

U2 - 10.1134/S1087659615010228

DO - 10.1134/S1087659615010228

M3 - Article

VL - 41

SP - 35

EP - 41

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 1

ER -

ID: 3936245