Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands : Synthesis, Structure, and Photophysical Properties. / Katkova, S. A.; Eliseev, I. I.; Mikherdov, A. S.; Sokolova, E. V.; Starova, G. L.; Kinzhalov, M. A.
в: Russian Journal of General Chemistry, Том 91, № 3, 03.2021, стр. 393-400.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands
T2 - Synthesis, Structure, and Photophysical Properties
AU - Katkova, S. A.
AU - Eliseev, I. I.
AU - Mikherdov, A. S.
AU - Sokolova, E. V.
AU - Starova, G. L.
AU - Kinzhalov, M. A.
N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.
PY - 2021/3
Y1 - 2021/3
N2 - Abstract: A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80% yields from the dimer [{Pt(ppy)Cl}2] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.
AB - Abstract: A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80% yields from the dimer [{Pt(ppy)Cl}2] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.
KW - isocyanides
KW - luminescence
KW - nitriles
KW - platinum complexes
KW - ANCILLARY LIGANDS
KW - PD(II)
KW - CENTER-DOT-PT
KW - REACTIVITY
KW - LUMINESCENCE PROPERTIES
KW - 2-PHENYLPYRIDINE
KW - DIAMINOCARBENE LIGANDS
KW - PI
KW - CHLORIDE ORGANOMETALLICS
KW - AGGREGATION
UR - http://www.scopus.com/inward/record.url?scp=85104495810&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/d40f041e-9dc0-3ef8-b2fb-bb9704e3cb3b/
U2 - 10.1134/s1070363221030099
DO - 10.1134/s1070363221030099
M3 - Article
AN - SCOPUS:85104495810
VL - 91
SP - 393
EP - 400
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 3
ER -
ID: 84917668