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Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands : Synthesis, Structure, and Photophysical Properties. / Katkova, S. A.; Eliseev, I. I.; Mikherdov, A. S.; Sokolova, E. V.; Starova, G. L.; Kinzhalov, M. A.

In: Russian Journal of General Chemistry, Vol. 91, No. 3, 03.2021, p. 393-400.

Research output: Contribution to journal › Article › peer-review

Harvard

Katkova, SA, Eliseev, II, Mikherdov, AS, Sokolova, EV, Starova, GL & Kinzhalov, MA 2021, 'Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties', Russian Journal of General Chemistry, vol. 91, no. 3, pp. 393-400. https://doi.org/10.1134/s1070363221030099, https://doi.org/10.1134/S1070363221030099

APA

Katkova, S. A., Eliseev, I. I., Mikherdov, A. S., Sokolova, E. V., Starova, G. L., & Kinzhalov, M. A. (2021). Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties. Russian Journal of General Chemistry, 91(3), 393-400. https://doi.org/10.1134/s1070363221030099, https://doi.org/10.1134/S1070363221030099

Vancouver

Katkova SA, Eliseev II, Mikherdov AS, Sokolova EV, Starova GL, Kinzhalov MA. Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties. Russian Journal of General Chemistry. 2021 Mar;91(3):393-400. https://doi.org/10.1134/s1070363221030099, https://doi.org/10.1134/S1070363221030099

Author

Katkova, S. A. ; Eliseev, I. I. ; Mikherdov, A. S. ; Sokolova, E. V. ; Starova, G. L. ; Kinzhalov, M. A. / Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands : Synthesis, Structure, and Photophysical Properties. In: Russian Journal of General Chemistry. 2021 ; Vol. 91, No. 3. pp. 393-400.

BibTeX

@article{b2b73c63f7074f48a132626e3cbbe3b1,
title = "Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands: Synthesis, Structure, and Photophysical Properties",
abstract = "Abstract: A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80% yields from the dimer [{Pt(ppy)Cl}2] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.",
keywords = "isocyanides, luminescence, nitriles, platinum complexes, ANCILLARY LIGANDS, PD(II), CENTER-DOT-PT, REACTIVITY, LUMINESCENCE PROPERTIES, 2-PHENYLPYRIDINE, DIAMINOCARBENE LIGANDS, PI, CHLORIDE ORGANOMETALLICS, AGGREGATION",
author = "Katkova, {S. A.} and Eliseev, {I. I.} and Mikherdov, {A. S.} and Sokolova, {E. V.} and Starova, {G. L.} and Kinzhalov, {M. A.}",
note = "Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = mar,
doi = "10.1134/s1070363221030099",
language = "English",
volume = "91",
pages = "393--400",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "3",

}

RIS

TY - JOUR

T1 - Cyclometalated Platinum(II) Complexes with Nitrile and Isocyanide Ligands

T2 - Synthesis, Structure, and Photophysical Properties

AU - Katkova, S. A.

AU - Eliseev, I. I.

AU - Mikherdov, A. S.

AU - Sokolova, E. V.

AU - Starova, G. L.

AU - Kinzhalov, M. A.

N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/3

Y1 - 2021/3

N2 - Abstract: A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80% yields from the dimer [{Pt(ppy)Cl}2] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.

AB - Abstract: A series of cyclometalated platinum(II) complexes with nitrile and isocyanide ligands (RCN and RNC; R = t-Bu, Bn, Ph) have been synthesized in 60–80% yields from the dimer [{Pt(ppy)Cl}2] (Hppy is 2-phenylpyridine) and the corresponding nitriles and isocyanides. The structure of the synthesized complexes was determined by mass spectrometry, IR and NMR spectroscopy, and X-ray diffraction. The contributions of different intermolecular interactions to the crystal packing were estimated by Hirshfeld surface analysis. Photophysical properties of the synthesized complexes in solution and solid state were studied.

KW - isocyanides

KW - luminescence

KW - nitriles

KW - platinum complexes

KW - ANCILLARY LIGANDS

KW - PD(II)

KW - CENTER-DOT-PT

KW - REACTIVITY

KW - LUMINESCENCE PROPERTIES

KW - 2-PHENYLPYRIDINE

KW - DIAMINOCARBENE LIGANDS

KW - PI

KW - CHLORIDE ORGANOMETALLICS

KW - AGGREGATION

UR - http://www.scopus.com/inward/record.url?scp=85104495810&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/d40f041e-9dc0-3ef8-b2fb-bb9704e3cb3b/

U2 - 10.1134/s1070363221030099

DO - 10.1134/s1070363221030099

M3 - Article

AN - SCOPUS:85104495810

VL - 91

SP - 393

EP - 400

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 3

ER -

ID: 84917668