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Coordination of Boron-centered Lewis Acids by organo-substituted Phosphanylboranes. / Marquardt, Christian; Kahoun, Tobias; Baumann, Josef; Timoshkin, Alexey Y.; Scheer, Manfred.

в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 643, № 21, 17.11.2017, стр. 1326-1330.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Marquardt, C, Kahoun, T, Baumann, J, Timoshkin, AY & Scheer, M 2017, 'Coordination of Boron-centered Lewis Acids by organo-substituted Phosphanylboranes', Zeitschrift fur Anorganische und Allgemeine Chemie, Том. 643, № 21, стр. 1326-1330. https://doi.org/10.1002/zaac.201700219

APA

Marquardt, C., Kahoun, T., Baumann, J., Timoshkin, A. Y., & Scheer, M. (2017). Coordination of Boron-centered Lewis Acids by organo-substituted Phosphanylboranes. Zeitschrift fur Anorganische und Allgemeine Chemie, 643(21), 1326-1330. https://doi.org/10.1002/zaac.201700219

Vancouver

Marquardt C, Kahoun T, Baumann J, Timoshkin AY, Scheer M. Coordination of Boron-centered Lewis Acids by organo-substituted Phosphanylboranes. Zeitschrift fur Anorganische und Allgemeine Chemie. 2017 Нояб. 17;643(21):1326-1330. https://doi.org/10.1002/zaac.201700219

Author

Marquardt, Christian ; Kahoun, Tobias ; Baumann, Josef ; Timoshkin, Alexey Y. ; Scheer, Manfred. / Coordination of Boron-centered Lewis Acids by organo-substituted Phosphanylboranes. в: Zeitschrift fur Anorganische und Allgemeine Chemie. 2017 ; Том 643, № 21. стр. 1326-1330.

BibTeX

@article{1084a1e44e944e518be24a5504aad92c,
title = "Coordination of Boron-centered Lewis Acids by organo-substituted Phosphanylboranes",
abstract = "The reactions of the monomeric phosphanylboranes Ph2P–BH2·NMe3 (1a) and tBuHP–BH2·NMe3 (1b) with the main group Lewis acids BH3 and BBr3 yield the adducts H3B·Ph2P–BH2·NMe3 (2a) and H3B·tBuHP–BH2·NMe3 (2b), Br3B·Ph2P–BH2·NMe3 (3a), and Br3B·tBuHP–BH2·NMe3 (3b). All these compounds were completely characterized by single-crystal X-ray structure analysis, NMR and IR spectroscopy as well as mass spectrometry and DFT computations. The secondary and tertiary phosphines 1a and 1b behave as classical Lewis bases to coordinate BX3 (X = H, Br) as terminal groups.",
keywords = "Adduct, Boron, Lewis acids, Phosphanylboranes, Phosphorus",
author = "Christian Marquardt and Tobias Kahoun and Josef Baumann and Timoshkin, {Alexey Y.} and Manfred Scheer",
year = "2017",
month = nov,
day = "17",
doi = "10.1002/zaac.201700219",
language = "English",
volume = "643",
pages = "1326--1330",
journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",
issn = "0044-2313",
publisher = "Wiley-Blackwell",
number = "21",

}

RIS

TY - JOUR

T1 - Coordination of Boron-centered Lewis Acids by organo-substituted Phosphanylboranes

AU - Marquardt, Christian

AU - Kahoun, Tobias

AU - Baumann, Josef

AU - Timoshkin, Alexey Y.

AU - Scheer, Manfred

PY - 2017/11/17

Y1 - 2017/11/17

N2 - The reactions of the monomeric phosphanylboranes Ph2P–BH2·NMe3 (1a) and tBuHP–BH2·NMe3 (1b) with the main group Lewis acids BH3 and BBr3 yield the adducts H3B·Ph2P–BH2·NMe3 (2a) and H3B·tBuHP–BH2·NMe3 (2b), Br3B·Ph2P–BH2·NMe3 (3a), and Br3B·tBuHP–BH2·NMe3 (3b). All these compounds were completely characterized by single-crystal X-ray structure analysis, NMR and IR spectroscopy as well as mass spectrometry and DFT computations. The secondary and tertiary phosphines 1a and 1b behave as classical Lewis bases to coordinate BX3 (X = H, Br) as terminal groups.

AB - The reactions of the monomeric phosphanylboranes Ph2P–BH2·NMe3 (1a) and tBuHP–BH2·NMe3 (1b) with the main group Lewis acids BH3 and BBr3 yield the adducts H3B·Ph2P–BH2·NMe3 (2a) and H3B·tBuHP–BH2·NMe3 (2b), Br3B·Ph2P–BH2·NMe3 (3a), and Br3B·tBuHP–BH2·NMe3 (3b). All these compounds were completely characterized by single-crystal X-ray structure analysis, NMR and IR spectroscopy as well as mass spectrometry and DFT computations. The secondary and tertiary phosphines 1a and 1b behave as classical Lewis bases to coordinate BX3 (X = H, Br) as terminal groups.

KW - Adduct

KW - Boron

KW - Lewis acids

KW - Phosphanylboranes

KW - Phosphorus

UR - http://www.scopus.com/inward/record.url?scp=85034994535&partnerID=8YFLogxK

U2 - 10.1002/zaac.201700219

DO - 10.1002/zaac.201700219

M3 - Article

AN - SCOPUS:85034994535

VL - 643

SP - 1326

EP - 1330

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 21

ER -

ID: 14471814