Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties. / Petukhova, Y.V.; Kudinova, A.A.; Bobrysheva, N.P.; Osmolowsky, M.G.; Alekseeva, E.V.; Levin, O.V.; Osmolovskaya, O.M.
в: Materials Science and Engineering B: Solid-State Materials for Advanced Technology, Том 255, 114519, 05.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties
AU - Petukhova, Y.V.
AU - Kudinova, A.A.
AU - Bobrysheva, N.P.
AU - Osmolowsky, M.G.
AU - Alekseeva, E.V.
AU - Levin, O.V.
AU - Osmolovskaya, O.M.
N1 - Publisher Copyright: © 2020 Elsevier B.V.
PY - 2020/5
Y1 - 2020/5
N2 - A novel approach to regulate nanoparticles morphology using capping agents (etidronic, succinic, tartaric and salicylic acids) in hydrothermal synthesis is presented. UV–Vis and FTIR spectra showed that influence of the capping agents is based on the interaction with particles surface during the solid phase formation. For na-VO 2 nanorods a 1st order phase transition at 275 K was demonstrated using vibration sample magnetometry. Differential scanning calorimetry showed that this transition is accompanied by 2nd order transition at 320 K. Decrease in rods thickness and length for sal-VO 2 and suc-VO 2 made the transition less expressed and its temperature lowered from 275 to 150 K. Addition of tartaric and etidronic acids led to change of particles shape from rods to spheres and eliminated all the transitional changes in magnetic properties. Charge-discharge tests revealed that initial discharge capacity of nanorods was 100 mA h g −1, which is three times higher than that of spheres.
AB - A novel approach to regulate nanoparticles morphology using capping agents (etidronic, succinic, tartaric and salicylic acids) in hydrothermal synthesis is presented. UV–Vis and FTIR spectra showed that influence of the capping agents is based on the interaction with particles surface during the solid phase formation. For na-VO 2 nanorods a 1st order phase transition at 275 K was demonstrated using vibration sample magnetometry. Differential scanning calorimetry showed that this transition is accompanied by 2nd order transition at 320 K. Decrease in rods thickness and length for sal-VO 2 and suc-VO 2 made the transition less expressed and its temperature lowered from 275 to 150 K. Addition of tartaric and etidronic acids led to change of particles shape from rods to spheres and eliminated all the transitional changes in magnetic properties. Charge-discharge tests revealed that initial discharge capacity of nanorods was 100 mA h g −1, which is three times higher than that of spheres.
KW - Capping agent
KW - Li-ion batteries
KW - Nanoparticle
KW - Semiconductor-metal phase transition
KW - Vanadium dioxide
KW - TRANSFORMATION
KW - ROUTE
KW - METAL-INSULATOR-TRANSITION
KW - PHASE
KW - NANORODS
KW - COMPOSITE
KW - OXOVANADIUM(IV) COMPLEXES
UR - http://www.scopus.com/inward/record.url?scp=85081679674&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/cdc7db86-bc51-3ecb-ac50-5d18c38c8663/
U2 - 10.1016/j.mseb.2020.114519
DO - 10.1016/j.mseb.2020.114519
M3 - Article
VL - 255
JO - Materials Science and Engineering B
JF - Materials Science and Engineering B
SN - 0921-5107
M1 - 114519
ER -
ID: 52388064