Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties

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Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties. / Petukhova, Y.V.; Kudinova, A.A.; Bobrysheva, N.P.; Osmolowsky, M.G.; Alekseeva, E.V.; Levin, O.V.; Osmolovskaya, O.M.

In: Materials Science and Engineering B: Solid-State Materials for Advanced Technology, Vol. 255, 114519, 05.2020.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{3e7161ac90a047cc8956d030bfcf4cac,

title = "Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties",

abstract = "A novel approach to regulate nanoparticles morphology using capping agents (etidronic, succinic, tartaric and salicylic acids) in hydrothermal synthesis is presented. UV–Vis and FTIR spectra showed that influence of the capping agents is based on the interaction with particles surface during the solid phase formation. For na-VO 2 nanorods a 1st order phase transition at 275 K was demonstrated using vibration sample magnetometry. Differential scanning calorimetry showed that this transition is accompanied by 2nd order transition at 320 K. Decrease in rods thickness and length for sal-VO 2 and suc-VO 2 made the transition less expressed and its temperature lowered from 275 to 150 K. Addition of tartaric and etidronic acids led to change of particles shape from rods to spheres and eliminated all the transitional changes in magnetic properties. Charge-discharge tests revealed that initial discharge capacity of nanorods was 100 mA h g −1, which is three times higher than that of spheres. ",

keywords = "Capping agent, Li-ion batteries, Nanoparticle, Semiconductor-metal phase transition, Vanadium dioxide, TRANSFORMATION, ROUTE, METAL-INSULATOR-TRANSITION, PHASE, NANORODS, COMPOSITE, OXOVANADIUM(IV) COMPLEXES",

author = "Y.V. Petukhova and A.A. Kudinova and N.P. Bobrysheva and M.G. Osmolowsky and E.V. Alekseeva and O.V. Levin and O.M. Osmolovskaya",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = may,

doi = "10.1016/j.mseb.2020.114519",

language = "English",

volume = "255",

journal = "Materials Science and Engineering B",

issn = "0921-5107",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Capping agents as a novel approach to control VO2 nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties

AU - Petukhova, Y.V.

AU - Kudinova, A.A.

AU - Bobrysheva, N.P.

AU - Osmolowsky, M.G.

AU - Alekseeva, E.V.

AU - Levin, O.V.

AU - Osmolovskaya, O.M.

PY - 2020/5

Y1 - 2020/5

N2 - A novel approach to regulate nanoparticles morphology using capping agents (etidronic, succinic, tartaric and salicylic acids) in hydrothermal synthesis is presented. UV–Vis and FTIR spectra showed that influence of the capping agents is based on the interaction with particles surface during the solid phase formation. For na-VO 2 nanorods a 1st order phase transition at 275 K was demonstrated using vibration sample magnetometry. Differential scanning calorimetry showed that this transition is accompanied by 2nd order transition at 320 K. Decrease in rods thickness and length for sal-VO 2 and suc-VO 2 made the transition less expressed and its temperature lowered from 275 to 150 K. Addition of tartaric and etidronic acids led to change of particles shape from rods to spheres and eliminated all the transitional changes in magnetic properties. Charge-discharge tests revealed that initial discharge capacity of nanorods was 100 mA h g −1, which is three times higher than that of spheres.

AB - A novel approach to regulate nanoparticles morphology using capping agents (etidronic, succinic, tartaric and salicylic acids) in hydrothermal synthesis is presented. UV–Vis and FTIR spectra showed that influence of the capping agents is based on the interaction with particles surface during the solid phase formation. For na-VO 2 nanorods a 1st order phase transition at 275 K was demonstrated using vibration sample magnetometry. Differential scanning calorimetry showed that this transition is accompanied by 2nd order transition at 320 K. Decrease in rods thickness and length for sal-VO 2 and suc-VO 2 made the transition less expressed and its temperature lowered from 275 to 150 K. Addition of tartaric and etidronic acids led to change of particles shape from rods to spheres and eliminated all the transitional changes in magnetic properties. Charge-discharge tests revealed that initial discharge capacity of nanorods was 100 mA h g −1, which is three times higher than that of spheres.

KW - Capping agent

KW - Li-ion batteries

KW - Nanoparticle

KW - Semiconductor-metal phase transition

KW - Vanadium dioxide

KW - TRANSFORMATION

KW - ROUTE

KW - METAL-INSULATOR-TRANSITION

KW - PHASE

KW - NANORODS

KW - COMPOSITE

KW - OXOVANADIUM(IV) COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85081679674&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/cdc7db86-bc51-3ecb-ac50-5d18c38c8663/

U2 - 10.1016/j.mseb.2020.114519

DO - 10.1016/j.mseb.2020.114519

M3 - Article

VL - 255

JO - Materials Science and Engineering B

JF - Materials Science and Engineering B

SN - 0921-5107

M1 - 114519

ER -

ID: 52388064