Aryl-Aryl Coupling of Salicylic Aldehydes through Oxidative CH-activation in Nickel Salen Derivatives

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Aryl-Aryl Coupling of Salicylic Aldehydes through Oxidative CH-activation in Nickel Salen Derivatives. / Yankin, Andrei N.; Lukyanov, Daniil A.; Beletskii, Evgenii V.; Bakulina, Olga Yu ; Vlasov, Petr S.; Levin, Oleg V.

в: ChemistrySelect, Том 4, № 30, 12.08.2019, стр. 8886-8890.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{21e03e633c9c4b2180049949f86c28f7,

title = "Aryl-Aryl Coupling of Salicylic Aldehydes through Oxidative CH-activation in Nickel Salen Derivatives",

abstract = "The preparative electrosynthetic procedure for gram-scale preparation of symmetric 4,4′-dihydroxy-3,3′-diformylbiphenyls from salicylic aldehydes via the intermediate formation of ethylene-bridged bis((2-hydroxybenzylidene)imino)nickel (II) complexes is reported for the first time. This procedure represents a practical route to the variety of rare bisphenol derivatives. The electrochemical aryl-aryl coupling via an oxidative CH – activation in NiSalens is exploited for facile and selective C−C bond formation.",

keywords = "Aldehydes, biaryls, C−C coupling, heterometallic complexes, polymerization, C-C coupling, REDOX PROCESSES, COMPLEXES, POLYMERIZATION, SCHIFF-BASES, ENERGY-STORAGE, LIGAND, CATALYSTS",

author = "Yankin, {Andrei N.} and Lukyanov, {Daniil A.} and Beletskii, {Evgenii V.} and Bakulina, {Olga Yu} and Vlasov, {Petr S.} and Levin, {Oleg V.}",

year = "2019",

month = aug,

day = "12",

doi = "10.1002/slct.201902385",

language = "English",

volume = "4",

pages = "8886--8890",

journal = "ChemistrySelect",

issn = "2365-6549",

publisher = "Wiley-Blackwell",

number = "30",

}

RIS

TY - JOUR

T1 - Aryl-Aryl Coupling of Salicylic Aldehydes through Oxidative CH-activation in Nickel Salen Derivatives

AU - Yankin, Andrei N.

AU - Lukyanov, Daniil A.

AU - Beletskii, Evgenii V.

AU - Bakulina, Olga Yu

AU - Vlasov, Petr S.

AU - Levin, Oleg V.

PY - 2019/8/12

Y1 - 2019/8/12

N2 - The preparative electrosynthetic procedure for gram-scale preparation of symmetric 4,4′-dihydroxy-3,3′-diformylbiphenyls from salicylic aldehydes via the intermediate formation of ethylene-bridged bis((2-hydroxybenzylidene)imino)nickel (II) complexes is reported for the first time. This procedure represents a practical route to the variety of rare bisphenol derivatives. The electrochemical aryl-aryl coupling via an oxidative CH – activation in NiSalens is exploited for facile and selective C−C bond formation.

AB - The preparative electrosynthetic procedure for gram-scale preparation of symmetric 4,4′-dihydroxy-3,3′-diformylbiphenyls from salicylic aldehydes via the intermediate formation of ethylene-bridged bis((2-hydroxybenzylidene)imino)nickel (II) complexes is reported for the first time. This procedure represents a practical route to the variety of rare bisphenol derivatives. The electrochemical aryl-aryl coupling via an oxidative CH – activation in NiSalens is exploited for facile and selective C−C bond formation.

KW - Aldehydes

KW - biaryls

KW - C−C coupling

KW - heterometallic complexes

KW - polymerization

KW - C-C coupling

KW - REDOX PROCESSES

KW - COMPLEXES

KW - POLYMERIZATION

KW - SCHIFF-BASES

KW - ENERGY-STORAGE

KW - LIGAND

KW - CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85070622729&partnerID=8YFLogxK

U2 - 10.1002/slct.201902385

DO - 10.1002/slct.201902385

M3 - Article

AN - SCOPUS:85070622729

VL - 4

SP - 8886

EP - 8890

JO - ChemistrySelect

JF - ChemistrySelect

SN - 2365-6549

IS - 30

ER -

ID: 45274516