Research output: Contribution to journal › Article › peer-review
Aryl-Aryl Coupling of Salicylic Aldehydes through Oxidative CH-activation in Nickel Salen Derivatives. / Yankin, Andrei N.; Lukyanov, Daniil A.; Beletskii, Evgenii V.; Bakulina, Olga Yu; Vlasov, Petr S.; Levin, Oleg V.
In: ChemistrySelect, Vol. 4, No. 30, 12.08.2019, p. 8886-8890.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Aryl-Aryl Coupling of Salicylic Aldehydes through Oxidative CH-activation in Nickel Salen Derivatives
AU - Yankin, Andrei N.
AU - Lukyanov, Daniil A.
AU - Beletskii, Evgenii V.
AU - Bakulina, Olga Yu
AU - Vlasov, Petr S.
AU - Levin, Oleg V.
PY - 2019/8/12
Y1 - 2019/8/12
N2 - The preparative electrosynthetic procedure for gram-scale preparation of symmetric 4,4′-dihydroxy-3,3′-diformylbiphenyls from salicylic aldehydes via the intermediate formation of ethylene-bridged bis((2-hydroxybenzylidene)imino)nickel (II) complexes is reported for the first time. This procedure represents a practical route to the variety of rare bisphenol derivatives. The electrochemical aryl-aryl coupling via an oxidative CH – activation in NiSalens is exploited for facile and selective C−C bond formation.
AB - The preparative electrosynthetic procedure for gram-scale preparation of symmetric 4,4′-dihydroxy-3,3′-diformylbiphenyls from salicylic aldehydes via the intermediate formation of ethylene-bridged bis((2-hydroxybenzylidene)imino)nickel (II) complexes is reported for the first time. This procedure represents a practical route to the variety of rare bisphenol derivatives. The electrochemical aryl-aryl coupling via an oxidative CH – activation in NiSalens is exploited for facile and selective C−C bond formation.
KW - Aldehydes
KW - biaryls
KW - C−C coupling
KW - heterometallic complexes
KW - polymerization
KW - C-C coupling
KW - REDOX PROCESSES
KW - COMPLEXES
KW - POLYMERIZATION
KW - SCHIFF-BASES
KW - ENERGY-STORAGE
KW - LIGAND
KW - CATALYSTS
UR - http://www.scopus.com/inward/record.url?scp=85070622729&partnerID=8YFLogxK
U2 - 10.1002/slct.201902385
DO - 10.1002/slct.201902385
M3 - Article
AN - SCOPUS:85070622729
VL - 4
SP - 8886
EP - 8890
JO - ChemistrySelect
JF - ChemistrySelect
SN - 2365-6549
IS - 30
ER -
ID: 45274516