Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Antimony(III) Iodide Complexes with Pyridine: Structures and bonding via three pnictogen bonds. / Pomogaeva, Anna V. ; Khoroshilova, Olesya V. ; Davydova, Elena I. ; Suslonov, Vitalii V. ; Timoshkin, Alexey Y. .
в: Zeitschrift fur Anorganische und Allgemeine Chemie, Том 647, № 7, 09.04.2021, стр. 687-695.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Antimony(III) Iodide Complexes with Pyridine: Structures and bonding via three pnictogen bonds
AU - Pomogaeva, Anna V.
AU - Khoroshilova, Olesya V.
AU - Davydova, Elena I.
AU - Suslonov, Vitalii V.
AU - Timoshkin, Alexey Y.
N1 - Publisher Copyright: © 2020 Wiley-VCH GmbH
PY - 2021/4/9
Y1 - 2021/4/9
N2 - Solid state structures of five new molecular complexes of SbI3 with Py have been determined by single crystal X‐ray structural analysis. In all complexes, all antimony atoms adopt a pseudo‐octahedral coordination geometry, which is completed by additional Sb···I contacts shorter than sum of van der Waals radii, with I‐Sb···I angles close to 180º. Analysis of the electrostatic potentials, the orbital interactions and topological analysis indicate that these contacts are due to the presence of Sb···I pnictogen bonds. The first example of triple pnictogen bond of SbI3 is reported.
AB - Solid state structures of five new molecular complexes of SbI3 with Py have been determined by single crystal X‐ray structural analysis. In all complexes, all antimony atoms adopt a pseudo‐octahedral coordination geometry, which is completed by additional Sb···I contacts shorter than sum of van der Waals radii, with I‐Sb···I angles close to 180º. Analysis of the electrostatic potentials, the orbital interactions and topological analysis indicate that these contacts are due to the presence of Sb···I pnictogen bonds. The first example of triple pnictogen bond of SbI3 is reported.
KW - Antimony triiodide
KW - Complexes
KW - Crystal structure
KW - Pnictogen bonds
KW - Pyridine
UR - http://www.scopus.com/inward/record.url?scp=85100196610&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/1c6f4641-6460-36a4-997e-992c34f1b4c0/
U2 - 10.1002/zaac.202000444
DO - 10.1002/zaac.202000444
M3 - Article
AN - SCOPUS:85100196610
VL - 647
SP - 687
EP - 695
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
SN - 0044-2313
IS - 7
ER -
ID: 71497328