Antimony(III) Iodide Complexes with Pyridine: Structures and bonding via three pnictogen bonds

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Antimony(III) Iodide Complexes with Pyridine: Structures and bonding via three pnictogen bonds. / Pomogaeva, Anna V. ; Khoroshilova, Olesya V. ; Davydova, Elena I. ; Suslonov, Vitalii V. ; Timoshkin, Alexey Y. .

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 647, No. 7, 09.04.2021, p. 687-695.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{1d04989c07fc4183954f819603464d64,

title = "Antimony(III) Iodide Complexes with Pyridine: Structures and bonding via three pnictogen bonds",

abstract = "Solid state structures of five new molecular complexes of SbI3 with Py have been determined by single crystal X‐ray structural analysis. In all complexes, all antimony atoms adopt a pseudo‐octahedral coordination geometry, which is completed by additional Sb···I contacts shorter than sum of van der Waals radii, with I‐Sb···I angles close to 180º. Analysis of the electrostatic potentials, the orbital interactions and topological analysis indicate that these contacts are due to the presence of Sb···I pnictogen bonds. The first example of triple pnictogen bond of SbI3 is reported.",

keywords = "Antimony triiodide, Complexes, Crystal structure, Pnictogen bonds, Pyridine",

author = "Pomogaeva, {Anna V.} and Khoroshilova, {Olesya V.} and Davydova, {Elena I.} and Suslonov, {Vitalii V.} and Timoshkin, {Alexey Y.}",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH GmbH",

year = "2021",

month = apr,

day = "9",

doi = "10.1002/zaac.202000444",

language = "English",

volume = "647",

pages = "687--695",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-Blackwell",

number = "7",

}

RIS

TY - JOUR

T1 - Antimony(III) Iodide Complexes with Pyridine: Structures and bonding via three pnictogen bonds

AU - Pomogaeva, Anna V.

AU - Khoroshilova, Olesya V.

AU - Davydova, Elena I.

AU - Suslonov, Vitalii V.

AU - Timoshkin, Alexey Y.

PY - 2021/4/9

Y1 - 2021/4/9

N2 - Solid state structures of five new molecular complexes of SbI3 with Py have been determined by single crystal X‐ray structural analysis. In all complexes, all antimony atoms adopt a pseudo‐octahedral coordination geometry, which is completed by additional Sb···I contacts shorter than sum of van der Waals radii, with I‐Sb···I angles close to 180º. Analysis of the electrostatic potentials, the orbital interactions and topological analysis indicate that these contacts are due to the presence of Sb···I pnictogen bonds. The first example of triple pnictogen bond of SbI3 is reported.

AB - Solid state structures of five new molecular complexes of SbI3 with Py have been determined by single crystal X‐ray structural analysis. In all complexes, all antimony atoms adopt a pseudo‐octahedral coordination geometry, which is completed by additional Sb···I contacts shorter than sum of van der Waals radii, with I‐Sb···I angles close to 180º. Analysis of the electrostatic potentials, the orbital interactions and topological analysis indicate that these contacts are due to the presence of Sb···I pnictogen bonds. The first example of triple pnictogen bond of SbI3 is reported.

KW - Antimony triiodide

KW - Complexes

KW - Crystal structure

KW - Pnictogen bonds

KW - Pyridine

UR - http://www.scopus.com/inward/record.url?scp=85100196610&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/1c6f4641-6460-36a4-997e-992c34f1b4c0/

U2 - 10.1002/zaac.202000444

DO - 10.1002/zaac.202000444

M3 - Article

AN - SCOPUS:85100196610

VL - 647

SP - 687

EP - 695

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

SN - 0044-2313

IS - 7

ER -

ID: 71497328